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Aldehydes as Carbon Radical Acceptors: Silver Nitrate Catalyzed Cascade Decarboxylation and Oxidative Cyclization toward Dihydroflavonoid Derivatives

文献类型：期刊论文

作者Yang, Wen-Chao1,2,5; Dai, Peng1,2; Luo, Kai1,2,5; Ji, Yi-Gang1,2,5; Wu, Lei1,2,3,4
刊名ADVANCED SYNTHESIS & CATALYSIS
出版日期2017-07-17
卷号359期号:14页码:2390-2395
关键词Ketones Decarboxylation Aldehydic C-h Bonds Oxidative Cyclization Diacylation
英文摘要Silver nitrate-catalyzed cascade decarboxylation and oxidative cyclization of alpha-oxocarboxylic acids, alkenes, and aldehydes is demonstrated for the first time. With ammonium persulfate as the oxidant, the cascade reactions afford dihydroflavonoid derivatives as products in moderate to good yields, exhibiting a broad substrate tolerance. Control experiments indicated that the mechanism includes a radical pathway with aldehydes as the carbon radical acceptors.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/39081]  
专题化学研究所_其它
作者单位1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China
2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China
3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
5.Nanjing Agr Univ, Coll Plant Protect, Nanjing 210095, Jiangsu, Peoples R China
推荐引用方式
GB/T 7714		 Yang, Wen-Chao,Dai, Peng,Luo, Kai,et al. Aldehydes as Carbon Radical Acceptors: Silver Nitrate Catalyzed Cascade Decarboxylation and Oxidative Cyclization toward Dihydroflavonoid Derivatives[J]. ADVANCED SYNTHESIS & CATALYSIS,2017,359(14):2390-2395.
APA Yang, Wen-Chao,Dai, Peng,Luo, Kai,Ji, Yi-Gang,&Wu, Lei.(2017).Aldehydes as Carbon Radical Acceptors: Silver Nitrate Catalyzed Cascade Decarboxylation and Oxidative Cyclization toward Dihydroflavonoid Derivatives.ADVANCED SYNTHESIS & CATALYSIS,359(14),2390-2395.
MLA Yang, Wen-Chao,et al."Aldehydes as Carbon Radical Acceptors: Silver Nitrate Catalyzed Cascade Decarboxylation and Oxidative Cyclization toward Dihydroflavonoid Derivatives".ADVANCED SYNTHESIS & CATALYSIS 359.14(2017):2390-2395.

入库方式： OAI收割

来源：化学研究所

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