中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Size Fractionation of Graphene Oxide Nanosheets via Controlled Directional Freezing

文献类型:期刊论文

作者Geng, Hongya1; Yao, Bowen2; Zhou, Jiajia3,4; Liu, Kai1; Bai, Guoying1; Li, Wenbo1; Song, Yanlin1; Shi, Gaoquan2; Doi, Masao4; Wang, Jianjun1,5
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
出版日期2017-09-13
卷号139期号:36页码:12517-12523
英文摘要The properties and functions of graphene oxide (GO)-based materials strongly depend on the lateral size and size distribution of GO nanosheets; therefore, GO and its derivatives with narrow size distributions are highly desired. Here we report the size fractionation of GO nanosheets by controlled directional freezing of GO aqueous dispersions. GO nanosheets with a narrow size distribution can be obtained by controlling the growth rate of the freezing front. This interesting phenomenon can be explained by the adsorption of GO nanosheets on the ice crystal surface in combination with the stratification of GO nanosheets at the ice growth front. Such a convenient size fractionation approach will be essential for practical applications of chemically modified graphene, including GO, reduced GO, and their assemblies or composites.
语种英语
源URL[http://ir.iccas.ac.cn/handle/121111/41079]  
专题化学研究所_绿色印刷实验室
作者单位1.Chinese Acad Sci, Inst Chem, Key Lab Green Printing, Beijing 100190, Peoples R China
2.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
3.Beihang Univ, Sch Chem, Minist Educ, Key Lab Bioinspired Smart Interfacial Sci & Techn, Beijing 100191, Peoples R China
4.Beihang Univ, Ctr Soft Matter Phys & Its Applicat, Beijing 100191, Peoples R China
5.Chinese Acad Sci, Inst Chem, Zhongguancun North First St 2, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Geng, Hongya,Yao, Bowen,Zhou, Jiajia,et al. Size Fractionation of Graphene Oxide Nanosheets via Controlled Directional Freezing[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(36):12517-12523.
APA Geng, Hongya.,Yao, Bowen.,Zhou, Jiajia.,Liu, Kai.,Bai, Guoying.,...&Wang, Jianjun.(2017).Size Fractionation of Graphene Oxide Nanosheets via Controlled Directional Freezing.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(36),12517-12523.
MLA Geng, Hongya,et al."Size Fractionation of Graphene Oxide Nanosheets via Controlled Directional Freezing".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.36(2017):12517-12523.

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来源:化学研究所

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