An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds
文献类型：期刊论文
| 作者 | Zheng, J; Cheng, R; Lin, JH; Yu, DH; Ma, LL; Jia, LA; Zhang, L; Wang, L; Xiao, JC; Liang, SH |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:12页码:3196-3200 |
| 关键词 | F-18-labeling Difluorocarbene Fluorine Sulfuration Trifluoromethylthiolation |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201611761 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Trifluoromethylthiolation by sulfuration of difluorocarbene with elemental sulfur is described for the first time, which overrides long-standing trifluoromethyl anion-based theory. Mechanistic elucidation reveals an unprecedented chemical process for the formation of thiocarbonyl fluoride and also enables transition-metal-mediated trifluoromethylthiolation and [F-18]trifluoromethylthiolation of alpha-bromo carbonyl compounds with broad substrate scope and compatibility. |
| 语种 | 英语 |
| WOS记录号 | WOS:000397329300010 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/27255]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Zheng, J,Cheng, R,Lin, JH,et al. An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(12):3196-3200. |
| APA | Zheng, J.,Cheng, R.,Lin, JH.,Yu, DH.,Ma, LL.,...&Liang, SH.(2017).An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(12),3196-3200. |
| MLA | Zheng, J,et al."An Unconventional Mechanistic Insight into SCF3 Formation from Difluorocarbene: Preparation of F-18-Labeled alpha-SCF3 Carbonyl Compounds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.12(2017):3196-3200. |
入库方式： OAI收割
来源：上海应用物理研究所
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