中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
ASSESSMENT OF USEFULNESS OF SYNCHROTRON RADIATION TECHNIQUES TO DETERMINE ARSENIC SPECIES IN HAIR AND RICE GRAIN SAMPLES

文献类型:期刊论文

作者Lin, J; Lin, GF; Li, YL; Gao, XY; Du, H; Jia, CG; Lu, HC; Golka, K; Shen, JH
刊名EXCLI JOURNAL
出版日期2017
卷号16页码:25-34
关键词Arsenic Speciation Synchrotron Radiation Biogeochemical Abnormality Arseniasis Microdistribution
ISSN号1611-2156
DOI10.17179/excli2016-785
文献子类期刊论文
英文摘要The arseniasis in Southwest Guizhou, China has been identified as a unique case of endemic arseniasis caused by exposure to indoor combustion of high As-content coal. Present investigation targeted the microdistribution and speciation of the element arsenic in human hair and environmental samples collected in one of the hyperendemic villages of arseniasis in the area. Analyses were performed by micro-beam X-ray fluorescence (mu-XRF) and X-ray absorption fine structure (XAFS). The total As level in hair samples of diagnosed patients was detected at almost the same level as in their asymptomatic neighbors. Concentrations in the lateral cut of hair samples were high-low-high (from surface to center). XAFS revealed the coexistence of both the As+3 and As+5 states in hair samples. However, the samples from patients displayed a tendency of higher As+3 / As+5 ratio than the asymptomatic fellow villagers. The mu-XRF mapping of rice grains shows that arsenic penetrates the endosperm, the major edible part of the grain, when rice grains were stored over the open fire of high As-content coal. Synchrotron radiation techniques are suitable to determine arsenic species concentrations in different parts of hair and rice grain samples. As arsenic penetrates the endosperm, rinsing the rice grains with water will remain largely ineffective.
语种英语
WOS记录号WOS:000391236800003
源URL[http://ir.sinap.ac.cn/handle/331007/27259]  
专题上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式
GB/T 7714
Lin, J,Lin, GF,Li, YL,et al. ASSESSMENT OF USEFULNESS OF SYNCHROTRON RADIATION TECHNIQUES TO DETERMINE ARSENIC SPECIES IN HAIR AND RICE GRAIN SAMPLES[J]. EXCLI JOURNAL,2017,16:25-34.
APA Lin, J.,Lin, GF.,Li, YL.,Gao, XY.,Du, H.,...&Shen, JH.(2017).ASSESSMENT OF USEFULNESS OF SYNCHROTRON RADIATION TECHNIQUES TO DETERMINE ARSENIC SPECIES IN HAIR AND RICE GRAIN SAMPLES.EXCLI JOURNAL,16,25-34.
MLA Lin, J,et al."ASSESSMENT OF USEFULNESS OF SYNCHROTRON RADIATION TECHNIQUES TO DETERMINE ARSENIC SPECIES IN HAIR AND RICE GRAIN SAMPLES".EXCLI JOURNAL 16(2017):25-34.

入库方式: OAI收割

来源:上海应用物理研究所

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