Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate
文献类型：期刊论文
| 作者 | Wang, R; Gao, H; Zhu, DM; Yang, TY; Zhang, XM; Li, L; Yin, GZ; Zhu, LN; Feng, ZJ; Li, XL |
| 刊名 | CARBON
 |
| 出版日期 | 2017 |
| 卷号 | 114页码:23-30 |
| ISSN号 | 0008-6223 |
| DOI | 10.1016/j.carbon.2016.11.077 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The dehydration kinetics of graphene oxide (GO) were investigated by in-situ two-dimensional grazing incident X-ray diffraction. We found that the interlayer spacing of the GO membrane gradually decreased as the annealing temperature increased and as time elapsed. Surprisingly, we observed the formation of an intermediate "water-rich" GO layers at 25 degrees C with an interlayer spacing of approximately 15.2 angstrom, which was caused by the intercalation of two additional layers of water into the interlayers of the GO membrane. Moreover, three types of water trapped in GO were clearly distinguished upon isothermal annealing at various temperatures. Below 160 degrees C, the removal of "bulk water" and "confined water" resulted in a smaller interlayer spacing and the preservation of oxygen-containing functional groups. At 160 degrees C or higher, "bound water" was removed and oxygen-containing functional groups were lost, which contributed to the reduction of GO. The dehydration behaviour and structural evolution of GO investigated here is useful for understanding and controlling the properties of GO membranes for permeation, separation and electronic applications. (C) 2016 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000393249600004 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/27290]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang, R,Gao, H,Zhu, DM,et al. Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate[J]. CARBON,2017,114:23-30. |
| APA | Wang, R.,Gao, H.,Zhu, DM.,Yang, TY.,Zhang, XM.,...&Li, XL.(2017).Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate.CARBON,114,23-30. |
| MLA | Wang, R,et al."Dehydration behaviour and structural evolution of graphene oxide membranes on silicon substrate".CARBON 114(2017):23-30. |
入库方式： OAI收割
来源：上海应用物理研究所
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