Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets
文献类型：期刊论文
| 作者 | Wang, T; Wang, WL; Lyu, Y; Xiong, K; Li, CY; Zhang, H; Zhan, ZP; Jiang, Z; Ding, YJ |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2017 |
| 卷号 | 38期号:4页码:691-698 |
| 关键词 | Porous Organic Polymer Heterogeneous Catalysis Asymmetric Hydroformylation Enhanced Enatioselectivity Chiral Nanopocket |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(17)62790-6 |
| 文献子类 | 期刊论文 |
| 英文摘要 | A new chiral monomer, (S)-5,5'-divinyl-BINAP, was successfully synthesized and embedded into two different porous organic polymers (Poly-1 and Poly-2). After loading a Rh species, the catalysts were applied for the heterogeneous asymmetric hydroformylation of styrene. Compared with the homogeneous BINAP analogue, the enantioselectivity of Rh/Poly-1 catalyst was drastically increased by approximately 70%. The improved enantioselectivity of the porous Rh/BINAP polymers was attributed to the presence of flexible chiral nanopockets resulting from the increased bulk of the R groups near the catalytic center. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000400419900009 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/27415]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang, T,Wang, WL,Lyu, Y,et al. Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets[J]. CHINESE JOURNAL OF CATALYSIS,2017,38(4):691-698. |
| APA | Wang, T.,Wang, WL.,Lyu, Y.,Xiong, K.,Li, CY.,...&Ding, YJ.(2017).Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets.CHINESE JOURNAL OF CATALYSIS,38(4),691-698. |
| MLA | Wang, T,et al."Porous Rh/BINAP polymers as efficient heterogeneous catalysts for asymmetric hydroformylation of styrene: Enhanced enantioselectivity realized by flexible chiral nanopockets".CHINESE JOURNAL OF CATALYSIS 38.4(2017):691-698. |
入库方式： OAI收割
来源：上海应用物理研究所
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