Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms
文献类型：期刊论文
| 作者 | Wang, LB; Li, HL; Zhang, WB; Zhao, X; Qiu, JX; Li, AW; Zheng, XS; Hu, ZP; Si, R; Zeng, J |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:17页码:4712-4718 |
| 关键词 | Hydrolysis Metal-support Interactions Rhodium Single-atom Catalysts Vanadium Dioxide |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201701089 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Supported metal nanocrystals have exhibited remarkable catalytic performance in hydrogen generation reactions, which is influenced and even determined by their supports. Accordingly, it is of fundamental importance to determine the direct relationship between catalytic performance and metal-support interactions. Herein, we provide a quantitative profile for exploring metal-support interactions by considering the highest occupied state in single-atom catalysts. The catalyst studied consisted of isolated Rh atoms dispersed on the surface of VO2 nanorods. It was observed that the activation energy of ammonia-borane hydrolysis changed when the substrate underwent a phase transition. Mechanistic studies indicate that the catalytic performance depended directly on the highest occupied state of the single Rh atoms, which was determined by the band structure of the substrates. Other metal catalysts, even with non-noble metals, that exhibited significant catalytic activity towards NH3BH3 hydrolysis were rationally designed by adjusting their highest occupied states. |
| 语种 | 英语 |
| WOS记录号 | WOS:000398576000003 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/27461]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Wang, LB,Li, HL,Zhang, WB,et al. Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(17):4712-4718. |
| APA | Wang, LB.,Li, HL.,Zhang, WB.,Zhao, X.,Qiu, JX.,...&Zeng, J.(2017).Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(17),4712-4718. |
| MLA | Wang, LB,et al."Supported Rhodium Catalysts for Ammonia-Borane Hydrolysis: Dependence of the Catalytic Activity on the Highest Occupied State of the Single Rhodium Atoms".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.17(2017):4712-4718. |
入库方式： OAI收割
来源：上海应用物理研究所
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