Synthesis and metal-support interaction of subnanometer copper-palladium bimetallic oxide clusters for catalytic oxidation of carbon monoxide
文献类型：期刊论文
| 作者 | Du, PP; Hu, XC; Wang, X; Ma, C; Du, M; Zeng, J; Jia, CJ; Huang, YY; Si, R |
| 刊名 | INORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2017 |
| 卷号 | 4期号:4页码:668-674 |
| ISSN号 | 2052-1553 |
| DOI | 10.1039/c6qi00535g |
| 文献子类 | 期刊论文 |
| 英文摘要 | Subnanometer oxide clusters with distinct metal-support interactions have attracted great interest due to their possible superiority in catalytic performance compared to that of conventional metal-oxide nanoparticles. In this paper, we report the solution-based chemical synthesis of a new type of copper-palladium bimetallic oxide clusters anchored to the surface of ceria nanorods. Revealed by aberrationcorrected high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) and X-ray absorption fine structure (XAFS) techniques, we have identified that both copper and palladium species are fully oxidized with dominant metal-support interaction contributions by a strongly bound M-O-x-Ce (M = Cu or Pd) structure. However, no direct bond between copper oxide and palladium oxide clusters, i.e. Cu-O-x-Pd, has been verified by experimental evidences, and thus no synergistic effect on the catalytic activity of bimetallic copper-palladium oxide clusters, compared to that of single metal (palladium) oxide clusters, has been demonstrated for the CO oxidation reaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000399196000010 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/27466]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Du, PP,Hu, XC,Wang, X,et al. Synthesis and metal-support interaction of subnanometer copper-palladium bimetallic oxide clusters for catalytic oxidation of carbon monoxide[J]. INORGANIC CHEMISTRY FRONTIERS,2017,4(4):668-674. |
| APA | Du, PP.,Hu, XC.,Wang, X.,Ma, C.,Du, M.,...&Si, R.(2017).Synthesis and metal-support interaction of subnanometer copper-palladium bimetallic oxide clusters for catalytic oxidation of carbon monoxide.INORGANIC CHEMISTRY FRONTIERS,4(4),668-674. |
| MLA | Du, PP,et al."Synthesis and metal-support interaction of subnanometer copper-palladium bimetallic oxide clusters for catalytic oxidation of carbon monoxide".INORGANIC CHEMISTRY FRONTIERS 4.4(2017):668-674. |
入库方式： OAI收割
来源：上海应用物理研究所
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