Extraction of lanthanide ions with N,N,N',N'-tetrabutyl-3-oxa-diglycolamide from nitric acid media
文献类型：期刊论文
| 作者 | Peng, XJ; Cui, Y; Ma, JF; Li, YL; Sun, GX |
| 刊名 | NUCLEAR SCIENCE AND TECHNIQUES
 |
| 出版日期 | 2017 |
| 卷号 | 28期号:6页码:- |
| 关键词 | Solvent-extraction Diglycolamide Dga N-dodecane Todga Complexation n Luminescence N'-dimethyl-n Malonamides N'-diphenyl-3-oxapentanediamide Elements Eu3++ |
| ISSN号 | 1001-8042 |
| DOI | 10.1007/s41365-017-0229-4 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Extractability and extraction mechanism of lanthanide ions were investigated by using a new extractant, N,N,N',N'-tetrabutyl-3-oxa-diglycolamide (TBDGA), in toluene from nitric acid media. The effects of HNO3 and TBDGA concentrations, and temperature, on extraction of lanthanide ions were studied. Stoichiometries of the main extracted species were HNO3 . TBDGA and M(NO3)(3)-3TBDGA (M = Er, Dy, Tb, Gd, La, Ce, Nd, Sm and Eu). The extracted species for metal ions were established to be ionic complex. In this complex, nitrate anion was not coordinated to the central ion. The extraction pattern increased gradually across the lanthanide ions series, showing enhanced affinity of TBDGA toward heavy lanthanide ions. Thermodynamic parameters were investigated for the exothermic extraction reaction. |
| WOS关键词 | SOLVENT-EXTRACTION ; DIGLYCOLAMIDE DGA ; N-DODECANE ; TODGA ; N,N'-DIMETHYL-N,N'-DIPHENYL-3-OXAPENTANEDIAMIDE ; COMPLEXATION ; LUMINESCENCE ; MALONAMIDES ; ELEMENTS ; EU3+ |
| 语种 | 英语 |
| WOS记录号 | WOS:000402895400015 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28652]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Peng, XJ,Cui, Y,Ma, JF,et al. Extraction of lanthanide ions with N,N,N',N'-tetrabutyl-3-oxa-diglycolamide from nitric acid media[J]. NUCLEAR SCIENCE AND TECHNIQUES,2017,28(6):-. |
| APA | Peng, XJ,Cui, Y,Ma, JF,Li, YL,&Sun, GX.(2017).Extraction of lanthanide ions with N,N,N',N'-tetrabutyl-3-oxa-diglycolamide from nitric acid media.NUCLEAR SCIENCE AND TECHNIQUES,28(6),-. |
| MLA | Peng, XJ,et al."Extraction of lanthanide ions with N,N,N',N'-tetrabutyl-3-oxa-diglycolamide from nitric acid media".NUCLEAR SCIENCE AND TECHNIQUES 28.6(2017):-. |
入库方式： OAI收割
来源：上海应用物理研究所
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