Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals
文献类型：期刊论文
| 作者 | Li, H; Liu, X; Qi, SQ; Xu, LL; Shi, GS; Ding, YH; Yan, XY; Huang, Y; Geng, JX |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2017 |
| 卷号 | 56期号:45页码:14090-14095 |
| 关键词 | Nonheme Iron Catalysts o Bond Homolysis High-spin Photodissociation Spectroscopy Electronic-structure Oxidation Reactions Complexes Photolysis Reactivity Nitride |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/ange.201707823 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Zeolites with molecular dimension pores are widely used in petrochemical and fine-chemical industries. While traditional solvothermal syntheses suffer from environmental, safety, and efficiency issues, the newly developed solvent-free synthesis is limited by zeolite crystal aggregation. Herein, we report well-dispersed and faceted silicalite ZSM-5 zeolite crystals obtained using a solvent-free synthesis facilitated by graphene oxide (GO). The selective interactions between the GO sheets and different facets, which are confirmed by molecular dynamics simulations, result in oriented growth of the ZSM-5 crystals along the c-axis. More importantly, the incorporation of GO sheets into the ZSM-5 crystals leads to the formation of mesopores. Consequently, the faceted ZSM-5 crystals exhibit hierarchical pore structures. This synthetic method is superior to conventional approaches because of the features of the ZSM-5 zeolite. |
| WOS关键词 | NONHEME IRON CATALYSTS ; O BOND HOMOLYSIS ; HIGH-SPIN ; PHOTODISSOCIATION SPECTROSCOPY ; ELECTRONIC-STRUCTURE ; OXIDATION REACTIONS ; COMPLEXES ; PHOTOLYSIS ; REACTIVITY ; NITRIDE |
| 语种 | 英语 |
| WOS记录号 | WOS:000413896400031 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28672]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Li, H,Liu, X,Qi, SQ,et al. Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2017,56(45):14090-14095. |
| APA | Li, H.,Liu, X.,Qi, SQ.,Xu, LL.,Shi, GS.,...&Geng, JX.(2017).Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,56(45),14090-14095. |
| MLA | Li, H,et al."Graphene Oxide Facilitates Solvent-Free Synthesis of Well-Dispersed, Faceted Zeolite Crystals".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 56.45(2017):14090-14095. |
入库方式： OAI收割
来源：上海应用物理研究所
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