Reprocessing Th-based spent fuels with di-1-methyl heptyl methyl phosphonate using centrifugal extractors
文献类型：期刊论文
| 作者 | Li, RF; Zhao, HG; Liu, CX; He, SH; Li, Z; Li, QN; Zhang, L |
| 刊名 | HYDROMETALLURGY
 |
| 出版日期 | 2017 |
| 卷号 | 174期号:-页码:84-90 |
| 关键词 | 3rd Phase-formation Nitric-acid Solution Solvent-extraction Thorium(Iv) Separation u(Vi) Uranium(Vi) Contactors Phosphate Reactor |
| ISSN号 | 0304-386X |
| DOI | 10.1016/j.hydromet.2017.09.006 |
| 文献子类 | 期刊论文 |
| 英文摘要 | In this paper, a reprocessing Th-based spent fuels process using di-1-methyl heptyl methyl phosphonate (DMHMP) as extractant was proposed and tested by multistage countercurrent extraction using batch simulation and centrifugal extractors. The analysis results of process samples show that the recovery of Th and U in 1A (co-extraction of Th and U), 1B (separation of Th from U) and 1C (stripping of U from organic to aqueous phase) section was more than 99.8% and 99.9%, respectively. The separation factor of Th from U and U from Th in 1B section was 5.9 x 10(3) and 7.1 x 10(3), respectively. Compared with Thorex process using TBP as extractant, the process could be operated under lower acidity and flow ratio of O:A due to the strong extraction ability of DMHMP. Thus, DMHMP would be a promising alternative extractant for Th-based spent fuels process. |
| WOS关键词 | 3RD PHASE-FORMATION ; NITRIC-ACID SOLUTION ; SOLVENT-EXTRACTION ; THORIUM(IV) ; SEPARATION ; U(VI) ; URANIUM(VI) ; CONTACTORS ; PHOSPHATE ; REACTOR |
| 语种 | 英语 |
| WOS记录号 | WOS:000416195200011 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28802]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Li, RF,Zhao, HG,Liu, CX,et al. Reprocessing Th-based spent fuels with di-1-methyl heptyl methyl phosphonate using centrifugal extractors[J]. HYDROMETALLURGY,2017,174(-):84-90. |
| APA | Li, RF.,Zhao, HG.,Liu, CX.,He, SH.,Li, Z.,...&Zhang, L.(2017).Reprocessing Th-based spent fuels with di-1-methyl heptyl methyl phosphonate using centrifugal extractors.HYDROMETALLURGY,174(-),84-90. |
| MLA | Li, RF,et al."Reprocessing Th-based spent fuels with di-1-methyl heptyl methyl phosphonate using centrifugal extractors".HYDROMETALLURGY 174.-(2017):84-90. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。