Semicrystalline Polymer Binary-Phase Structure Templated Quasi-Block Graft Copolymers
文献类型：期刊论文
| 作者 | Guan, JP; Wang, YY; Xing, CY; Ye, LJ; Li, YJ; Li, JY |
| 刊名 | JOURNAL OF PHYSICAL CHEMISTRY B
 |
| 出版日期 | 2017 |
| 卷号 | 121期号:31页码:7508-7518 |
| 关键词 | Transfer Radical Polymerization Ionic Liquid Gel Electrolytes Poly(Vinylidene Fluoride) Anionic Polymerizations Hydroxide Conductivity Exchange Membrane Proton Transport Tie Molecules Fuel-cells |
| ISSN号 | 1520-6106 |
| DOI | 10.1021/acs.jpcb.7b05069 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Herein, we report a simple strategy to synthesize quasi-block graft copolymers using the binary phase structure of semicrystalline polymers as the template. An unsaturated ionic liquid, 1-vinyl-3-butylimidazolium bis (trifluoromethylsulfonyl) imide ([VBIm] [TFSI]), is thermodynamically miscible with poly(vinylidene fluoride-co-hexa-fluoropropylene) (P(VDF-co-HFP)) in solution. The solidification of P(VDF-co-HFP)/[VBIm] [TFSI] blend leads to the expelling of ILs from the crystalline region and the ILs are only located in the amorphous region. The electron-beam irradiation (EBI) at the solid state of the blends results in the locally grafting of the ILs onto the polymer blocks in the amorphous region, while the EBI does not affect the chemical structure of the crystalline region. Therefore, the quasi-block graft copolymers were achieved with IL-grafted blocks segregated by the unmodified blocks. The achieved block copolymers can be microphase separated into the various nanostructures, as the block copolymers with well-defined structure, upon varying the grafting ratios. The microphase separated quasi-block grafted copolymers exhibit excellent mechanical properties and good electrical properties. The elongation at break is 480% and the stress at break is as high as 30 MPa for the sample with the lamellar-like structure having the grafting ratio of 45.4 wt%. |
| WOS关键词 | TRANSFER RADICAL POLYMERIZATION ; IONIC LIQUID ; GEL ELECTROLYTES ; POLY(VINYLIDENE FLUORIDE) ; ANIONIC POLYMERIZATIONS ; HYDROXIDE CONDUCTIVITY ; EXCHANGE MEMBRANE ; PROTON TRANSPORT ; TIE MOLECULES ; FUEL-CELLS |
| 语种 | 英语 |
| WOS记录号 | WOS:000407655800013 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28812]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Guan, JP,Wang, YY,Xing, CY,et al. Semicrystalline Polymer Binary-Phase Structure Templated Quasi-Block Graft Copolymers[J]. JOURNAL OF PHYSICAL CHEMISTRY B,2017,121(31):7508-7518. |
| APA | Guan, JP,Wang, YY,Xing, CY,Ye, LJ,Li, YJ,&Li, JY.(2017).Semicrystalline Polymer Binary-Phase Structure Templated Quasi-Block Graft Copolymers.JOURNAL OF PHYSICAL CHEMISTRY B,121(31),7508-7518. |
| MLA | Guan, JP,et al."Semicrystalline Polymer Binary-Phase Structure Templated Quasi-Block Graft Copolymers".JOURNAL OF PHYSICAL CHEMISTRY B 121.31(2017):7508-7518. |
入库方式： OAI收割
来源：上海应用物理研究所
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