Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems
文献类型：期刊论文
| 作者 | Li, X; Wang, K; Xie, MY; Wu, Z; Xie, LD |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2017 |
| 卷号 | 33期号:3页码:454-459 |
| 关键词 | Binary-system h System Equilibria Li |
| ISSN号 | 1005-9040 |
| DOI | 10.1007/s40242-017-6282-z |
| 文献子类 | 期刊论文 |
| 英文摘要 | Phase diagrams for the CsF-UF4 and CsF-ThF4 systems were modeled in the present work through computational thermodynamics. The associate solution model with various complex species(CsMF5, Cs2MF6 and Cs3MF7; M=Th, U) was used to thermodynamically describe the binary molten salts. A total of ten intermediate phases were treated as stoichiometric compounds with their Gibbs energies modeled according to the Neumann-Kopp rule. All these model parameters were optimized by the least squares procedure until good coincidence was achieved between the calculated results and most of the experimental data. The derived thermodynamic parameters will be merged into the multicomponent CsF-LiF-BeF2-ThF4-UF4 database for analyzing physicochemical behavior of CsF in the fuel salt of the molten salt breeder reactor. |
| WOS关键词 | BINARY-SYSTEM ; H SYSTEM ; EQUILIBRIA ; LI |
| 语种 | 英语 |
| WOS记录号 | WOS:000404375600022 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28875]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Li, X,Wang, K,Xie, MY,et al. Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(3):454-459. |
| APA | Li, X,Wang, K,Xie, MY,Wu, Z,&Xie, LD.(2017).Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(3),454-459. |
| MLA | Li, X,et al."Thermodynamic and Phase Diagram Modeling of CsF-MF4(M=U, Th) Systems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.3(2017):454-459. |
入库方式： OAI收割
来源：上海应用物理研究所
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