Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems
文献类型：期刊论文
| 作者 | Xie, MY; Li, X; Ding, YP; Zhang, GX |
| 刊名 | CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
 |
| 出版日期 | 2017 |
| 卷号 | 33期号:5页码:794-798 |
| 关键词 | Molten-salt Reactor Energy-storage Binary-system Thorium |
| ISSN号 | 1005-9040 |
| DOI | 10.1007/s40242-017-7033-x |
| 文献子类 | 期刊论文 |
| 英文摘要 | The phase equilibria for the MCI2-ThCI4(M: Mg, Ca, Sr, Ba) binary systems were critically evaluated and optimized based upon the CALPHAD approach.. The substitutional solution model(SSM) was used to describe the liquid phase. All the. intermediate compounds were treated as stoichiometric compounds of which Gibbs energies comply with the Neumann-Kopp rule. Thermodynamic model parameters optimization for respective phases was conducted by the least squares minimization procedure with required input data available from experimental measurements. Satisfactory agreements between all calculated results and experimental data were achieved which demonstrates that thermodynamic databases for the MCI2-ThCI4(M: Mg, Ca, Sr, Ba) binary systems were ultimately derived. in the present work allowing safe extrapolation into multi-component system for guiding relative industrial applications. |
| WOS关键词 | MOLTEN-SALT REACTOR ; ENERGY-STORAGE ; BINARY-SYSTEM ; THORIUM |
| 语种 | 英语 |
| WOS记录号 | WOS:000412790500017 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28876]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Xie, MY,Li, X,Ding, YP,et al. Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(5):794-798. |
| APA | Xie, MY,Li, X,Ding, YP,&Zhang, GX.(2017).Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(5),794-798. |
| MLA | Xie, MY,et al."Thermodynamic Description of the MCl2-ThCl4 (M: Mg, Ca, Sr, Ba) Systems".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.5(2017):794-798. |
入库方式： OAI收割
来源：上海应用物理研究所
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