Thorium copper phosphides: more diverse metal-phosphorus and phosphorus-phosphorus interactions than U analogues
文献类型：期刊论文
| 作者 | Jin, GB; Malliakas, CD; Lin, J |
| 刊名 | DALTON TRANSACTIONS
 |
| 出版日期 | 2017 |
| 卷号 | 46期号:36页码:12041-12052 |
| 关键词 | Crystal-structure Structural Chemistry Uranium Chalcogenides Electronic-structure Transport-properties Black Phosphorus Rare-earth Polyphosphides Complexes Pnictides |
| ISSN号 | 1477-9226 |
| DOI | 10.1039/c7dt02145c |
| 文献子类 | 期刊论文 |
| 英文摘要 | To explore the chemical analogy between thorium and heavier actinides in soft anionic environments, three new thorium phosphides (ThCuP2, beta-ThCu2P2, and ThCu5P3) have been prepared through solid-state reactions using CuI as a reaction promoter. The structure of ThCuP2 can be described as a filled UTe2-type with both dimeric P-2(4-) and monomeric P3- anions, in which Th is coordinated by eight P atoms in a bicapped trigonal prismatic arrangement and Cu is tetrahedrally coordinated by four P atoms. beta-ThCu2P2 contains only P3- anions and is isostructural with BaCu2S2. In this structure, Th is coordinated by seven P atoms in monocapped trigonal prismatic geometry and Cu is tetrahedrally coordinated by four P atoms. ThCu5P3 adopts the YCo5P3-type structure consisting of P3- anions. This structure contains Th atoms coordinated by six P atoms in a trigonal prismatic arrangement and Cu atoms that are either tetrahedrally coordinated by four P atoms or square pyramidally coordinated by five P atoms. Electric resistivity measurements and electronic structure calculations on beta-ThCu2P2 indicate a metal. These new compounds may be charge-balanced and formulated as Th4+Cu+(P-2(4-))(1/2)P3-, Th4+(Cu+)(2)(P3-)2, and Th4+(Cu+)(5)(P3-)(3), respectively. The structural, bonding, and property relationships between these Th compounds and related actinide and rare-earth phases are discussed. Titled compounds display more diverse ion-ion interactions and different electronic structures from those in UCuP2 and UCu2P2 that were synthesized under similar experimental conditions, suggesting divergence of thorium-phosphide chemistry from uranium-phosphide chemistry. |
| WOS关键词 | CRYSTAL-STRUCTURE ; STRUCTURAL CHEMISTRY ; URANIUM CHALCOGENIDES ; ELECTRONIC-STRUCTURE ; TRANSPORT-PROPERTIES ; BLACK PHOSPHORUS ; RARE-EARTH ; POLYPHOSPHIDES ; COMPLEXES ; PNICTIDES |
| 语种 | 英语 |
| WOS记录号 | WOS:000411224500010 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28878]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 推荐引用方式 GB/T 7714 | Jin, GB,Malliakas, CD,Lin, J. Thorium copper phosphides: more diverse metal-phosphorus and phosphorus-phosphorus interactions than U analogues[J]. DALTON TRANSACTIONS,2017,46(36):12041-12052. |
| APA | Jin, GB,Malliakas, CD,&Lin, J.(2017).Thorium copper phosphides: more diverse metal-phosphorus and phosphorus-phosphorus interactions than U analogues.DALTON TRANSACTIONS,46(36),12041-12052. |
| MLA | Jin, GB,et al."Thorium copper phosphides: more diverse metal-phosphorus and phosphorus-phosphorus interactions than U analogues".DALTON TRANSACTIONS 46.36(2017):12041-12052. |
入库方式： OAI收割
来源：上海应用物理研究所
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