A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions
文献类型：期刊论文
| 作者 | Qie, MY; Lin, J; Kong, F; Silver, MA; Yue, ZH; Wang, XM; Zhang, LJ; Bao, HL; Albrecht-Schmitt, TE; Wang, JQ |
| 刊名 | INORGANIC CHEMISTRY
 |
| 出版日期 | 2018 |
| 卷号 | 57期号:3页码:1676-1683 |
| 关键词 | Electronic-energy Levels Lanthanide Aquo Ions Tellurite-sulfate Compounds Structural Evolution Magnetic-properties Uranium Phosphites Uranyl Iodate Frameworks Selenites Lattice |
| ISSN号 | 0020-1669 |
| DOI | 10.1021/acs.inorgchem.7b03116 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The exploration of phase formation in the f-element-bearing iodate selenate system has resulted in 14 novel rare-earth-containing iodate selenates, Ln(IO3)(SeO4) (Ln = La, Ce, Pr, Nd; LnISeO-1), Ln(IO3)(SeO4)(H2O) (Ln = Sm, Eu; LnISeO-2), and Ln(IO3)(SeO4)(H2O)(2)center dot H2O (Ln = Gd, Dy, Ho, Er, Tm, Yb, Lu, Y; LnISeO-3), as well as two new thorium iodate selenates, Th(OH)(IO3)(SeO4)(H2O) (ThISeO-1) and Th(IO3)2(SeO4) (ThISeO-2). LnISeO-3 and ThISeO-2 crystallize in the chiral space group P2(1)2(1)2(1), while LnISeO-1, LnISeO-2, and ThISeO-1 crystallize in the centrosymmetric space group P2(1)/c. The numbers of both coordinating and hydrating water molecules crystallized in LnISeO-1, LnISeO-2, and LnISeO-3 increase along these three series, in line with the increasingly negative values of hydration enthalpies of heavier trivalent lanthanide ions. Such a systematic change in compositions, especially the first coordination sphere of Ln, further induces structural rearrangements, including coordination number and dimensional reductions. More specifically, the structures of LnISeO-1, LnISeO-2, and LnISeO-3 have undergone transitions from 2D Ln-oxo layers with 10-coordinate Ln centers to 1D Ln-oxo chains with 9-coordinate Ln centers and then to OD Ln-oxo monomers with 8 coordinate Ln centers, respectively. The formation and characterization of this large family of Ln/Th iodate selenates suggest that such a mixed-anion system not only exhibits richer structural chemistry but also can be capable of generating intriguing properties, such as the second-harmonic generation (SHG) effect. |
| 语种 | 英语 |
| WOS记录号 | WOS:000424730800083 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28907]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Qie, MY 2.Lin, J 3.Kong, F 4.Silver, MA 5.Yue, ZH 6.Wang, XM 7.Zhang, LJ 8.Bao, HL 9.Albrecht-Schmitt, TE 10.Wang, JQ |
| 推荐引用方式 GB/T 7714 | Qie, MY,Lin, J,Kong, F,et al. A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions[J]. INORGANIC CHEMISTRY,2018,57(3):1676-1683. |
| APA | Qie, MY.,Lin, J.,Kong, F.,Silver, MA.,Yue, ZH.,...&Wang, JQ.(2018).A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions.INORGANIC CHEMISTRY,57(3),1676-1683. |
| MLA | Qie, MY,et al."A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions".INORGANIC CHEMISTRY 57.3(2018):1676-1683. |
入库方式： OAI收割
来源：上海应用物理研究所
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