Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages
文献类型：期刊论文
| 作者 | Cao, LP; Wang, PP; Miao, XR; Dong, YH; Wang, H; Duan, HH; Yu, Y; Li, XP; Stang, PJ |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2018 |
| 卷号 | 140期号:22页码:7005-7011 |
| ISSN号 | 0002-7863 |
| 关键词 | Metal-organic Frameworks Rational Design Networks Chemistry Hydrogen Crystalline Complexes Polyhedra Cuboctahedron Metallacycles |
| DOI | 10.1021/jacs.8b03856 |
| 文献子类 | 期刊论文 |
| 英文摘要 | Recently, porous framework materials with various network-type structures have been constructed via several different approaches, such as coordination interactions, reversible covalent bonds, and non-covalent interactions. Here, we have combined the concepts of supramolecular coordination complex (SCC) and metal-organic framework to offer a new strategy to construct a diamondoid supramolecular coordination framework (SCF) from an adamantanoid supramolecular coordination cage as the tetrahedral node and a difunctional Pt(II) ligand as the linear linker via stepwise orientation-induced supramolecular coordination. The adamantanoid supra molecular coordination cage has four uncoordinated pyridyl groups, which serve as the four vertexes of the tetrahedral geometry in the diamondoid framework. As a result, this diamondoid SCF exhibits an adamantanoid-to-adamantanoid substructure with two sets of pores, including the interior cavity of the adamantanoid cage and the extended adamantanoid space between the individual cages in the framework. In addition, the shape-controllable and highly ordered self-assembly of nanometer-sized diamondoid SCF is observed as micrometer-sized regular octahedrons by evaporation under heating in DMSO. This study demonstrates the potential application of supramolecular coordination complexes in the precise construction of highly regulated porous framework materials. |
| 语种 | 英语 |
| WOS记录号 | WOS:000434895200041 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28971]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Cao, LP 2.Wang, PP 3.Miao, XR 4.Dong, YH 5.Wang, H 6.Duan, HH 7.Yu, Y 8.Li, XP 9.Stang, PJ |
| 推荐引用方式 GB/T 7714 | Cao, LP,Wang, PP,Miao, XR,et al. Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018,140(22):7005-7011. |
| APA | Cao, LP.,Wang, PP.,Miao, XR.,Dong, YH.,Wang, H.,...&Stang, PJ.(2018).Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,140(22),7005-7011. |
| MLA | Cao, LP,et al."Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140.22(2018):7005-7011. |
入库方式： OAI收割
来源：上海应用物理研究所
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