Electrochemical deposition of neodymium in LiF-CaF2 from Nd2O3 assisted by AlF3
文献类型：期刊论文
| 作者 | Chen, Z; She, CF; Zheng, HY; Huang, W; Zhu, TJ; Jiang, F; Gong, Y; Li, QN |
| 刊名 | ELECTROCHIMICA ACTA
 |
| 出版日期 | 2018 |
| 卷号 | 261页码:289-295 |
| 关键词 | Eutectic Licl-kcl Co-reduction Molten Fluorides Extraction Aluminum Alloys Melts Salt Electrodes Gadolinium |
| ISSN号 | 0013-4686 |
| DOI | 10.1016/j.electacta.2017.12.147 |
| 文献子类 | 期刊论文 |
| 英文摘要 | This paper investigated the co-reduction process of Al-Nd alloys and the electrochemical extraction of neodymium from neodymium oxide in LiF-CaF2 melt. Nd(III) at a tungsten electrode was reduced to Nd(0) through a one-step process involving the exchange of three electrons: Nd(III) + 3e(-) = Nd(0). The fluorination of Nd2O3 by AlF3 produced Nd(III) ions in the LiF-CaF2 molten salts. The co-reduction behavior of Nd(III) and Al(III) ions was studied on a W electrode in the LiF-CaF2-AlF3-Nd2O3 system. Four types of intermetallic Al-Nd compound were detected through cyclic voltammetry and open circuit chronopotentiometry. The Nd3Al and NdAl phases were identified through X-ray diffraction, and the NdAl3 and Nd3Al11 phases were characterized by a scanning electron microscope equipped with an energy dispersive spectrometer. (c) 2017 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000424635600034 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/28994]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Chen, Z 2.She, CF 3.Zheng, HY 4.Huang, W 5.Zhu, TJ 6.Jiang, F 7.Gong, Y 8.Li, QN |
| 推荐引用方式 GB/T 7714 | Chen, Z,She, CF,Zheng, HY,et al. Electrochemical deposition of neodymium in LiF-CaF2 from Nd2O3 assisted by AlF3[J]. ELECTROCHIMICA ACTA,2018,261:289-295. |
| APA | Chen, Z.,She, CF.,Zheng, HY.,Huang, W.,Zhu, TJ.,...&Li, QN.(2018).Electrochemical deposition of neodymium in LiF-CaF2 from Nd2O3 assisted by AlF3.ELECTROCHIMICA ACTA,261,289-295. |
| MLA | Chen, Z,et al."Electrochemical deposition of neodymium in LiF-CaF2 from Nd2O3 assisted by AlF3".ELECTROCHIMICA ACTA 261(2018):289-295. |
入库方式： OAI收割
来源：上海应用物理研究所
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