The structural isomerism in gold nanoclusters
文献类型：期刊论文
| 作者 | Xu, WW; Zeng, XC; Gao, Y |
| 刊名 | NANOSCALE
 |
| 出版日期 | 2018 |
| 卷号 | 10期号:20页码:9476-9483 |
| 关键词 | Cis-trans Isomerization Metal Nanoclusters Clusters Nanoparticles Molecules Chirality Size |
| ISSN号 | 2040-3364 |
| DOI | 10.1039/c8nr02284d |
| 文献子类 | 期刊论文 |
| 英文摘要 | The isomerism in thiolate-protected gold (Au) nanoclusters is important for the understanding of structure-property correlations and the design of Au nanoclusters with specific structures and properties. Although recent studies have identified stereoisomerism, the understanding of structural isomerism is still lacking. Herein, we identified three distinct mechanisms of structural isomerism (i.e., core isomerism, staple isomerism, and complex isomerism) based on the crystallized isomers of thiolate-protected Au nanoclusters, and these mechanisms can be viewed as analogous to those of the structural isomerism in organic molecules (i.e., chain isomerism, point isomerism, and functional isomerism). Using the discovered core isomerism and staple isomerism, two Au-28(SR)(20) isomers are predicted and their synthesis feasibilities are illuminated. These new insights into the structural isomerism can facilitate rational design of new isomers of thiolate-protected Au nanoclusters and guide future experimental synthesis. |
| 语种 | 英语 |
| WOS记录号 | WOS:000433260300007 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/29181]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Xu, WW 2.Zeng, XC 3.Gao, Y |
| 推荐引用方式 GB/T 7714 | Xu, WW,Zeng, XC,Gao, Y. The structural isomerism in gold nanoclusters[J]. NANOSCALE,2018,10(20):9476-9483. |
| APA | Xu, WW,Zeng, XC,&Gao, Y.(2018).The structural isomerism in gold nanoclusters.NANOSCALE,10(20),9476-9483. |
| MLA | Xu, WW,et al."The structural isomerism in gold nanoclusters".NANOSCALE 10.20(2018):9476-9483. |
入库方式： OAI收割
来源：上海应用物理研究所
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