Trifunctional C@MnO Catalyst for Enhanced Stable Simultaneously Catalytic Removal of Formaldehyde and Ozone
文献类型：期刊论文
| 作者 | Wang, HC; Huang, ZW; Jiang, Z; Jiang, Z; Zhang, Y; Zhang, ZX; Shangguan, WF |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2018 |
| 卷号 | 8期号:4页码:3164-3180 |
| 关键词 | Supported Manganese Oxides Room-temperature Benzene Oxidation Activated Carbon Water-vapor By-products Pore-size Decomposition Adsorption Spectroscopy |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.8b00309 |
| 文献子类 | 期刊论文 |
| 英文摘要 | The key challenge for controlling low concentration volatile organic compounds (VOCs) is to develop technology capable of operating under mild conditions in a cost-effective manner. Meanwhile, ozone (O-3) is another dangerous air pollutant and byproducts of many emerging air quality control technologies, such as plasma and electrostatic precipitators. To address these multiple challenges, we report here a design strategy capable of achieving the following trifunctions (i.e., efficiently VOCs adsorption enrichment, ozone destruction, and stable VOCs degradation) from the synergistic effect of adsorption center encapsulation and catalytic active sites optimization using 2D manganese(II) monoxide nanosheets decorated carbon spheres with hierarchical core shell structure. Carbonous residues in the as-synthesized MnOx matrices played a key role for in situ generating homogeneous dispersed unsaturated MnO during the annealing of the as-synthesized C@MnOx in the flow of argon under a proper calcination temperature (550 degrees C). The formation of the intimacy interface between MnO and carbon not only facilitates the adsorption and subsequent catalytic reaction but also results in a gatekeeper effect on the protection of the carbon sphere against the etching of O-3. Such a composite architecture achieved the highest stable removal efficiency (100% for CO2 ppm of formaldehyde and 180 ppm of O-3 simultaneously) and 100% CO2 selectivity under a GHSV of 60000 mL h(-1) g(-1) These findings thus open up a way to address current multiple challenges in air quality control using a single hierarchical core shell structure. |
| 语种 | 英语 |
| WOS记录号 | WOS:000430154100062 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/29197]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Wang, HC 2.Huang, ZW 3.Jiang, Z 4.Jiang, Z 5.Zhang, Y 6.Zhang, ZX 7.Shangguan, WF |
| 推荐引用方式 GB/T 7714 | Wang, HC,Huang, ZW,Jiang, Z,et al. Trifunctional C@MnO Catalyst for Enhanced Stable Simultaneously Catalytic Removal of Formaldehyde and Ozone[J]. ACS CATALYSIS,2018,8(4):3164-3180. |
| APA | Wang, HC.,Huang, ZW.,Jiang, Z.,Jiang, Z.,Zhang, Y.,...&Shangguan, WF.(2018).Trifunctional C@MnO Catalyst for Enhanced Stable Simultaneously Catalytic Removal of Formaldehyde and Ozone.ACS CATALYSIS,8(4),3164-3180. |
| MLA | Wang, HC,et al."Trifunctional C@MnO Catalyst for Enhanced Stable Simultaneously Catalytic Removal of Formaldehyde and Ozone".ACS CATALYSIS 8.4(2018):3164-3180. |
入库方式： OAI收割
来源：上海应用物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。