X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain
文献类型：期刊论文
| 作者 | Luo, M; Zhang, ML; Yan, WS; Wang, LH; Jiang, Z |
| 刊名 | JOURNAL OF THE AMERICAN CERAMIC SOCIETY
 |
| 出版日期 | 2018 |
| 卷号 | 101期号:5页码:2130-2136 |
| 关键词 | Fine-structure Co Speciation Alumina Microstructure Jingdezhen Dynasties Catalysts Glasses Yuan |
| ISSN号 | 0002-7820 |
| DOI | 10.1111/jace.15353 |
| 文献子类 | 期刊论文 |
| 英文摘要 | A series of cobalt blue pigments, which were synthesized based on the chemical compositions of the blue pigments in Kangxi blue and white porcelain, were investigated by Co, Mn, and Fe K-edge and L-2,L-3-edge X-ray absorption spectroscopy to determine the oxidation states and species of the elements and to discern their impact on the blue color. The results reveal that Co is bivalent and mainly located at tetrahedral sites, which is the main parameter controlling the blue color. Mn is mainly present as Mn2+, or CoxZn1-xAl2O4 and Fe is mainly present as Fe3+. In particular, Fe3+ substitutes the Al in CoAl2O4 and occupies octahedral sites with a high Mn content. All the synthetic cobalt blue pigments can form a solid solution with various end-members or an intermediate solution spinel. The spectroscopic determination of the oxidation states and speciation of Co, Mn, and Fe furthers understanding of the coloration of blue pigments in blue and white porcelain. |
| 语种 | 英语 |
| WOS记录号 | WOS:000426513900038 |
| 源URL | [http://ir.sinap.ac.cn/handle/331007/29210]  |
| 专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
| 作者单位 | 1.Luo, M 2.Zhang, ML 3.Yan, WS 4.Wang, LH 5.Jiang, Z |
| 推荐引用方式 GB/T 7714 | Luo, M,Zhang, ML,Yan, WS,et al. X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY,2018,101(5):2130-2136. |
| APA | Luo, M,Zhang, ML,Yan, WS,Wang, LH,&Jiang, Z.(2018).X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain.JOURNAL OF THE AMERICAN CERAMIC SOCIETY,101(5),2130-2136. |
| MLA | Luo, M,et al."X-ray absorption spectroscopy study of synthetic cobalt blue pigments similar to Kangxi blue and white porcelain".JOURNAL OF THE AMERICAN CERAMIC SOCIETY 101.5(2018):2130-2136. |
入库方式： OAI收割
来源：上海应用物理研究所
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