Highly efficient silylcyanation of ketones by a catalytic double activation method using lewis acid and N-oxide catalysts
文献类型：期刊论文
| 作者 | Chen, FX; Feng, XM; Qin, B; Zhang, GL; Jiang, YZ; Feng, XM, Sichuan Univ, Sichuan Key LGreen Chem & Technol, Coll Chem, Chengdu 610064, Peoples R China. |
| 刊名 | SYNLETT
 |
| 出版日期 | 2003 |
| 期号 | 4页码:558_560 |
| 关键词 | Cyanohydrins Double Activation Catalysis Ketones N-oxides Schiff Bases |
| ISSN号 | 0936-5214 |
| 产权排序 | 3 |
| 英文摘要 | An efficient protocol for addition of TMSCN to ketones by employing 3 mol% achiral Schiff base-Ti(IV) complex as the Lewis acid and 3 mol% N-oxide as the Lewis base in a manner of double activation was described. Aromatic, aliphatic, cyclic and heterocyclic ketones all gave the racemic O-TMS cyanohydrins in good to excellent yields (up to 99%) under mild conditions. |
| 学科主题 | Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000181584100025 |
| 公开日期 | 2011-07-08 |
| 源URL | [http://210.75.237.14/handle/351003/17399]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 通讯作者 | Feng, XM, Sichuan Univ, Sichuan Key LGreen Chem & Technol, Coll Chem, Chengdu 610064, Peoples R China. |
| 推荐引用方式 GB/T 7714 | Chen, FX,Feng, XM,Qin, B,et al. Highly efficient silylcyanation of ketones by a catalytic double activation method using lewis acid and N-oxide catalysts[J]. SYNLETT,2003(4):558_560. |
| APA | Chen, FX,Feng, XM,Qin, B,Zhang, GL,Jiang, YZ,&Feng, XM, Sichuan Univ, Sichuan Key LGreen Chem & Technol, Coll Chem, Chengdu 610064, Peoples R China..(2003).Highly efficient silylcyanation of ketones by a catalytic double activation method using lewis acid and N-oxide catalysts.SYNLETT(4),558_560. |
| MLA | Chen, FX,et al."Highly efficient silylcyanation of ketones by a catalytic double activation method using lewis acid and N-oxide catalysts".SYNLETT .4(2003):558_560. |
入库方式： OAI收割
来源：成都生物研究所
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