A Facile and Efficient Approach to N-Protected-beta-Sulfinylenamines via C-Sulfinylation of Enamides and Enecarbamates
文献类型：期刊论文
| 作者 | Li, Yinhui; Cheng, Ke; Lu, Xiaoxia; Sun, Jian; Lu, XX, Chinese Acad Sci, Nat Prod Res Ctr, Chengdu Inst Biol, Chengdu 610041, Peoples R China |
| 刊名 | ADVANCED SYNTHESIS & CATALYSIS
 |
| 出版日期 | 2010 |
| 卷号 | 352期号:11-12页码:1876-1880 |
| 关键词 | Enamides Enecarbamates Lewis Base Sodium Phenylsulfinate/methyltrichlorosilane (Phso2na/mesicl3) C-sulfinylation |
| ISSN号 | 1615-4150 |
| 产权排序 | 1 |
| 英文摘要 | A practical method has been developed for the C-sulfinylation of enamides and enecarbamates using sodium phenylsulfinate/methyltrichlorosilane (PhSO2Na/MeSiCl3) as the sulfinylating reagent and N,N-dimethylacetamide (DMAc) as the Lewis base promoter. which allows for the preparation of a variety of N-protected-beta-sulfinylenamines in high yields and good stereoselectivities. The Lewis base is found to be important for both the in situ generation of the active sulfinylating species (PhSOCl) and the sulfinylation step. |
| 学科主题 | Chemistry, Applied ; Chemistry, Organic |
| 语种 | 英语 |
| WOS记录号 | WOS:000281654500012 |
| 资助机构 | National Science Foundation of China [20732006, 20972152, 20972153] ; National Science Foundation of China [20732006, 20972152, 20972153] ; National Science Foundation of China [20732006, 20972152, 20972153] ; National Science Foundation of China [20732006, 20972152, 20972153] |
| 公开日期 | 2011-07-08 |
| 源URL | [http://210.75.237.14/handle/351003/18355]  |
| 专题 | 成都生物研究所_天然产物研究 |
| 通讯作者 | Lu, XX, Chinese Acad Sci, Nat Prod Res Ctr, Chengdu Inst Biol, Chengdu 610041, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yinhui,Cheng, Ke,Lu, Xiaoxia,et al. A Facile and Efficient Approach to N-Protected-beta-Sulfinylenamines via C-Sulfinylation of Enamides and Enecarbamates[J]. ADVANCED SYNTHESIS & CATALYSIS,2010,352(11-12):1876-1880. |
| APA | Li, Yinhui,Cheng, Ke,Lu, Xiaoxia,Sun, Jian,&Lu, XX, Chinese Acad Sci, Nat Prod Res Ctr, Chengdu Inst Biol, Chengdu 610041, Peoples R China.(2010).A Facile and Efficient Approach to N-Protected-beta-Sulfinylenamines via C-Sulfinylation of Enamides and Enecarbamates.ADVANCED SYNTHESIS & CATALYSIS,352(11-12),1876-1880. |
| MLA | Li, Yinhui,et al."A Facile and Efficient Approach to N-Protected-beta-Sulfinylenamines via C-Sulfinylation of Enamides and Enecarbamates".ADVANCED SYNTHESIS & CATALYSIS 352.11-12(2010):1876-1880. |
入库方式： OAI收割
来源：成都生物研究所
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