中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 成都生物研究所
  3. 中国科学院成都生物研究所
  4. 天然产物研究
Stereoselective Synthesis of 2-C-Acetonyl-2-Deoxy-D-Galactosides using 1,2-Cyclopropaneacetylated Sugar as Novel Glycosyl Donor

文献类型：期刊论文

作者Tian, Qiang; Xu, Liyan; Ma, Xiaofeng; Zou, Wei; Shao, Huawu; Shao, HW, Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China
刊名ORGANIC LETTERS
出版日期2010
卷号12期号:3页码:540-543
产权排序1
英文摘要1,2-Cyclopropaneacetylated sugar is an effective glycosyl donor, which reacted with various glycosyl acceptors including monosaccharides, amino acids and other alcohols in the presence of BF3 center dot OEt2 or TMSOTf. The glycosylation is stereoselective in favor of beta-anomeric products with BF3 center dot OEt2 as catalyst, whereas TMSOTf-catalyzed glycosylation prefers the alpha-anomeric products. 2-C-Acetonyl-2-deoxy-D-galactosides were obtained in good yields.
学科主题Chemistry ; Organic
资助机构Chinese Academy of Sciences ; National Science Foundation of China [20972151] ; Chinese Academy of Sciences ; National Science Foundation of China [20972151] ; Chinese Academy of Sciences ; National Science Foundation of China [20972151] ; Chinese Academy of Sciences ; National Science Foundation of China [20972151]
公开日期2011-07-08
源URL[http://210.75.237.14/handle/351003/22542]  
专题成都生物研究所_天然产物研究
通讯作者Shao, HW, Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China
推荐引用方式
GB/T 7714		 Tian, Qiang,Xu, Liyan,Ma, Xiaofeng,et al. Stereoselective Synthesis of 2-C-Acetonyl-2-Deoxy-D-Galactosides using 1,2-Cyclopropaneacetylated Sugar as Novel Glycosyl Donor[J]. ORGANIC LETTERS,2010,12(3):540-543.
APA Tian, Qiang,Xu, Liyan,Ma, Xiaofeng,Zou, Wei,Shao, Huawu,&Shao, HW, Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China.(2010).Stereoselective Synthesis of 2-C-Acetonyl-2-Deoxy-D-Galactosides using 1,2-Cyclopropaneacetylated Sugar as Novel Glycosyl Donor.ORGANIC LETTERS,12(3),540-543.
MLA Tian, Qiang,et al."Stereoselective Synthesis of 2-C-Acetonyl-2-Deoxy-D-Galactosides using 1,2-Cyclopropaneacetylated Sugar as Novel Glycosyl Donor".ORGANIC LETTERS 12.3(2010):540-543.

入库方式： OAI收割

来源：成都生物研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。