Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones with chiral sulfoxide-phosphine ligands
文献类型:期刊论文
作者 | Liao, J; Li, D (reprint author), Hubei Univ Technol, Coll Chem & Chem Engn, Wuhan 430068, Peoples R China.; Li, D (reprint author), Jingchu Univ Technol, Hubei Collaborat Innovat Ctr Targeted Antitumor, Jingmen 448000, Peoples R China.; Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China.; Yang, TT; Zhang, YL; Cao, P; Wang, M; Li, L; Li, D |
刊名 | TETRAHEDRON
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出版日期 | 2016 |
卷号 | 72期号:21页码:2707-2711 |
关键词 | Copper Catalysis Conjugate Addition Acyclic Enones Chiral Ligand Sulfoxideephosphine |
DOI | 10.1016/j.tet.2015.12.062 |
产权排序 | 2 |
文献子类 | Article |
英文摘要 | The copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones was achieved with chiral sulfoxide-phosphine (SOP) ligands. This process showed good functional group tolerance and gave the 1, 4-adducts with excellent enantioselectivities (up to 96% ee). (C) 2015 Elsevier Ltd. All rights reserved. |
学科主题 | Chemistry |
语种 | 英语 |
资助机构 | National Natural Science Foundation of China [21472184, 21572218, 21272226, 21402186] ; National Natural Science Foundation of China [21472184, 21572218, 21272226, 21402186] ; Hubei University of Technology ; Hubei University of Technology ; Western-Light Foundation of Chinese Academy of Sciences ; Western-Light Foundation of Chinese Academy of Sciences ; National Natural Science Foundation of China [21472184, 21572218, 21272226, 21402186] ; National Natural Science Foundation of China [21472184, 21572218, 21272226, 21402186] ; Hubei University of Technology ; Hubei University of Technology ; Western-Light Foundation of Chinese Academy of Sciences ; Western-Light Foundation of Chinese Academy of Sciences |
源URL | [http://210.75.237.14/handle/351003/28193] ![]() |
专题 | 成都生物研究所_天然产物研究 |
通讯作者 | Li, D (reprint author), Hubei Univ Technol, Coll Chem & Chem Engn, Wuhan 430068, Peoples R China.; Li, D (reprint author), Jingchu Univ Technol, Hubei Collaborat Innovat Ctr Targeted Antitumor, Jingmen 448000, Peoples R China.; Liao, J (reprint author), Chinese Acad Sci, Chengdu Inst Biol, Nat Prod Res Ctr, Chengdu 610041, Peoples R China. |
推荐引用方式 GB/T 7714 | Liao, J,Li, D ,Li, D ,et al. Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones with chiral sulfoxide-phosphine ligands[J]. TETRAHEDRON,2016,72(21):2707-2711. |
APA | Liao, J.,Li, D .,Li, D .,Liao, J .,Yang, TT.,...&Li, D.(2016).Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones with chiral sulfoxide-phosphine ligands.TETRAHEDRON,72(21),2707-2711. |
MLA | Liao, J,et al."Copper-catalyzed enantioselective conjugate addition of diethylzinc to acyclic enones with chiral sulfoxide-phosphine ligands".TETRAHEDRON 72.21(2016):2707-2711. |
入库方式: OAI收割
来源:成都生物研究所
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