C-I center dot center dot center dot pi Halogen Bonding Driven Supramolecular Helix of Bilateral N-Amidothioureas Bearing beta-Turns
文献类型：期刊论文
| 作者 | Liu, Maili4; Mo, Yirong1,2; Li, Zhao3; Cao, Jinlian3; Yan, Xiaosheng3; He, Wenbin3; Li, Xiaorui3; Jiang, Yun-Bao3 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2017-05-17 |
| 卷号 | 139期号:19页码:6605-6610 |
| DOI | 10.1021/jacs.6b13171 |
| 文献子类 | Article |
| 英文摘要 | We report the first example of C-I center dot center dot center dot pi halogen bonding driven supramolecular helix in highly dilute solution of micromolar concentration, using alanine based bilateral I-substituted N-amidothioureas that contain helical fragments, the beta-turn structures. The halogen bonding interactions afford head-to-tail linkages that help to propagate the helicity of the helical fragments. In support of this action of the halogen bonding, chiral amplification was observed in the supra molecular helix formed in acetonitrile solution. The present finding provides alternative tools in the design of self-assembling macromolecules. |
| WOS关键词 | ANION RECOGNITION ; MAJORITY-RULES ; PROTEINS ; IODIDE ; COMPLEXES ; CHIRALITY ; PEPTIDES ; ROTAXANE ; THIOUREA ; BENZENE |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000401781900021 |
| 资助机构 | NSF of China(21275121 ; NSF of China(21275121 ; Program for Changjiang Scholars and Innovative Research Team in University(IRT13036) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT13036) ; 21435003 ; 21435003 ; 91427304 ; 91427304 ; 21521004 ; 21521004 ; J1310024) ; J1310024) ; NSF of China(21275121 ; NSF of China(21275121 ; Program for Changjiang Scholars and Innovative Research Team in University(IRT13036) ; Program for Changjiang Scholars and Innovative Research Team in University(IRT13036) ; 21435003 ; 21435003 ; 91427304 ; 91427304 ; 21521004 ; 21521004 ; J1310024) ; J1310024) |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/11312]  |
| 专题 | 武汉物理与数学研究所_磁共振基础研究部 |
| 作者单位 | 1.Western Michigan Univ, Dept Chem, Kalamazoo, MI 49008 USA 2.Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 3.Xiamen Univ, MOE Key Lab Spectrochem Anal & Instrumentat, Collaborat Innovat Ctr Chem Energy Mat IChEM, Dept Chem,Coll Chem & Chem Engn, Xiamen 361005, Peoples R China 4.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Maili,Mo, Yirong,Li, Zhao,et al. C-I center dot center dot center dot pi Halogen Bonding Driven Supramolecular Helix of Bilateral N-Amidothioureas Bearing beta-Turns[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2017,139(19):6605-6610. |
| APA | Liu, Maili.,Mo, Yirong.,Li, Zhao.,Cao, Jinlian.,Yan, Xiaosheng.,...&Jiang, Yun-Bao.(2017).C-I center dot center dot center dot pi Halogen Bonding Driven Supramolecular Helix of Bilateral N-Amidothioureas Bearing beta-Turns.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,139(19),6605-6610. |
| MLA | Liu, Maili,et al."C-I center dot center dot center dot pi Halogen Bonding Driven Supramolecular Helix of Bilateral N-Amidothioureas Bearing beta-Turns".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 139.19(2017):6605-6610. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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