Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts
文献类型：期刊论文
| 作者 | Tao, Duan-Jian3; Cao, Zhi-Jun3; Zhao, Xin3; He, Fei-Qjang3; Zhou, Yan3; Huang, Kuan1; Zheng, An-Min2 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
 |
| 出版日期 | 2018-05-16 |
| 卷号 | 57期号:19页码:6654-6663 |
| DOI | 10.1021/acs.lecr.8b00535 |
| 文献子类 | Article |
| 英文摘要 | Improving the catalytic efficiency in the hydration of olefins to alcohols is an important yet challenging issue in acid catalysis. Herein, a series of novel superacidic polyoxometalate-based ionic hybrids were prepared and employed as catalysts for highly efficient indirect hydration of olefins to corresponding alcohols. Several characterization techniques such as FT-IR spectra, XRD, SEM, and P-31 MAS NMR spectroscopy were performed to characterize the structures of these superacid hybrids and their acid properties. The results show that the catalytic performances of ionic hybrids were closely related to their acidic strength. The superacidic ionic hybrid [BPy-SO3H-OTf]PW was found to be the best active catalyst to obtain the corresponding alcohols with good yields. The catalytic efficiency in indirect hydration process using superacidic ionic hybrid catalysts is obviously superior to that of direct hydration, which thus opens up a new way to improve the efficiency of the current hydration process. |
| WOS关键词 | REACTIVE-DISTILLATION PROCESS ; SOLID ACID CATALYSTS ; SELECTIVE OXIDATION ; ROOM-TEMPERATURE ; LIQUID CATALYST ; CYCLOHEXANOL ; ESTERIFICATION ; TRANSESTERIFICATION ; DEPOLYMERIZATION ; CYCLOPENTANOL |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000432752800008 |
| 资助机构 | National Natural Science Foundations of China(21566011 ; National Natural Science Foundations of China(21566011 ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; 31570560) ; 31570560) ; National Natural Science Foundations of China(21566011 ; National Natural Science Foundations of China(21566011 ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Jiangxi Province Sponsored Programs for Distinguished Young Scholars(20162BCB23026) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; Science & Technology Programs of Jiangxi Province Department of Education(GJJ160272) ; 31570560) ; 31570560) |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/11981]  |
| 专题 | 武汉物理与数学研究所_磁共振应用研究部 |
| 作者单位 | 1.Nanchang Univ, Sch Resources Environm & Chem Engn, Minist Educ, Key Lab Poyang Lake Environm & Resource Utilizat, Nanchang 330031, Jiangxi, Peoples R China 2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Hubei, Peoples R China 3.Jiangxi Normal Univ, Coll Chem & Chem Engn, Inst Adv Mat, Nanchang 330022, Jiangxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tao, Duan-Jian,Cao, Zhi-Jun,Zhao, Xin,et al. Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2018,57(19):6654-6663. |
| APA | Tao, Duan-Jian.,Cao, Zhi-Jun.,Zhao, Xin.,He, Fei-Qjang.,Zhou, Yan.,...&Zheng, An-Min.(2018).Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,57(19),6654-6663. |
| MLA | Tao, Duan-Jian,et al."Highly Efficient Indirect Hydration of Olefins to Alcohols Using Superacidic Polyoxometalate-Based Ionic Hybrids Catalysts".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 57.19(2018):6654-6663. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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