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SrB5O7F3 Functionalized with [B5O9F3](6-) Chromophores: Accelerating the Rational Design of Deep-Ultraviolet Nonlinear Optical Materials

文献类型：期刊论文

作者Zhou, Xin2; Pan, Shilie3; Yang, Zhihua3; Wang, Liying2; Zhang, Bingbing3; Zhang, Min3; Mutailipu, Miriding1,3
刊名ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
出版日期2018-05-22
卷号57期号:21页码:6095-6099
关键词Borates Deep-ultraviolet Fluorooxoborate Functionalized Chromophore Nonlinear Optical Materials
DOI10.1002/anie.201802058
文献子类Article
英文摘要Fluorooxoborates, benefiting from the large optical band gap, high anisotropy, and ever-greater possibility to form non-centrosymmetric structures activated by the large polarization of [BOxF4-x]((x+1)-) building blocks, have been considered as the new fertile fields for searching the ultraviolet (UV) and deep-UV nonlinear optical (NLO) materials. Herein, we report the first asymmetric alkaline-earth metal fluorooxoborate SrB5O7F3, which is rationally designed by taking the classic Sr2Be2B2O7 (SBBO) as a maternal structure. Its [B5O9F3](6-) fundamental building block with near-planar configuration composed by two edge-sharing [B3O6F2](5-) rings in SrB5O7F3 has not been reported in any other borates. Solid state F-19 and B-11 magic-angle spinning NMR spectroscopy verifies the presence of covalent B-F bonds in SrB5O7F3. Property characterizations reveal that SrB5O7F3 possesses the optical properties required for deep-UV NLO applications, which make SrB5O7F3 a promising crystal that could produce deep-UV coherent light by the direct SHG process.
WOS关键词2ND-HARMONIC GENERATION ; KBBF FAMILY ; CRYSTAL ; BORATE ; FLUOROOXOBORATE ; KBE2BO3F2 ; SR ; SR2BE2B2O7 ; LI2B6O9F2 ; LI2B3O4F3
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000432710100017
资助机构Natural Science Foundation of China(51702356 ; Natural Science Foundation of China(51702356 ; National Key Research Project(2016YFB0402104) ; National Key Research Project(2016YFB0402104) ; National National Basic Research Program of China(2014CB648400) ; National National Basic Research Program of China(2014CB648400) ; West Light Foundation of the Chinese Academy of Sciences(2016-YJRC-2) ; West Light Foundation of the Chinese Academy of Sciences(2016-YJRC-2) ; 81625011 ; 81625011 ; 51425206 ; 51425206 ; 91622107 ; 91622107 ; 21501194) ; 21501194) ; Natural Science Foundation of China(51702356 ; Natural Science Foundation of China(51702356 ; National Key Research Project(2016YFB0402104) ; National Key Research Project(2016YFB0402104) ; National National Basic Research Program of China(2014CB648400) ; National National Basic Research Program of China(2014CB648400) ; West Light Foundation of the Chinese Academy of Sciences(2016-YJRC-2) ; West Light Foundation of the Chinese Academy of Sciences(2016-YJRC-2) ; 81625011 ; 81625011 ; 51425206 ; 51425206 ; 91622107 ; 91622107 ; 21501194) ; 21501194)
源URL[http://ir.wipm.ac.cn/handle/112942/11987]  
专题武汉物理与数学研究所_磁共振应用研究部
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Key Lab Magnet Resonance Biol Syst, State Key Lab Magnet Resonance & Atom & Mol Phys, Natl Ctr Magnet Resonance Wuhan,Wuhan Inst Phys &, Wuhan 430071, Hubei, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Funct Mat & Devices Special Environm, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, 40-1 South Beijing Rd, Urumqi 830011, Peoples R China
推荐引用方式
GB/T 7714		 Zhou, Xin,Pan, Shilie,Yang, Zhihua,et al. SrB5O7F3 Functionalized with [B5O9F3](6-) Chromophores: Accelerating the Rational Design of Deep-Ultraviolet Nonlinear Optical Materials[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(21):6095-6099.
APA Zhou, Xin.,Pan, Shilie.,Yang, Zhihua.,Wang, Liying.,Zhang, Bingbing.,...&Mutailipu, Miriding.(2018).SrB5O7F3 Functionalized with [B5O9F3](6-) Chromophores: Accelerating the Rational Design of Deep-Ultraviolet Nonlinear Optical Materials.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(21),6095-6099.
MLA Zhou, Xin,et al."SrB5O7F3 Functionalized with [B5O9F3](6-) Chromophores: Accelerating the Rational Design of Deep-Ultraviolet Nonlinear Optical Materials".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.21(2018):6095-6099.

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来源：武汉物理与数学研究所

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