Symmetrization reaction of mercurated ferrocenylimines. X-ray crystal structure of [Hg{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NC6H4-4-Br)}(2)]
文献类型：期刊论文
| 作者 | Yuan, HZ; Liu, YH; Wu, YJ; Huo, SQ |
| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 1997-04-28 |
| 卷号 | 534期号:1-2页码:7-13 |
| 关键词 | Symmetrization Mercury Iron Ferrocene Crystal Structure |
| ISSN号 | 0022-328X |
| 文献子类 | Article |
| 英文摘要 | The symmetrization reaction of mercurated anils of benzoylferrocene 1 was easily achieved by refluxing 1 and PPh3 in CHCl3 solution, and afforded the symmetrized products [Hg{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NAr)}(2)] (Ar = a variety of substituted phenyls and beta-naphthyl) 2. During the reaction the organometallic complex salts [RHgPPh3]Cl formed; this can disproportionate to give the symmetrized products. The molecular structure of [Hg(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NC6H4-4-Br)}(2)] has been determined by single-crystal X-ray analysis. It crystallizes in the triclinic space group P (1) over bar, with a = 13.001(4), b = 13.029(2), c = 12.236(2)Angstrom, alpha = 103.00(1), beta = 104.10(2), gamma = 78.86(2)degrees and Z = 2. Refinement led to R = 0.027 (Rw = 0.037) using 3271 unique reflections with I > 3 sigma(1). The distance between N(2) and Hg is 2.981(6)Angstrom, shorter than the sum of van der Waals radii of N and Hg (3.05-3.15 Angstrom), indicating an intramolecular coordination of N(2) and Hg. The 1(H) NMR spectra of [Hg{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NAr)}(2)] (Ar = C6H4-2-Cl and 2-naphthyl) show that both compounds exist as rotamers in solution. |
| WOS关键词 | BENZOYLFERROCENE ; COMPLEXES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:A1997XH60100002 |
| 出版者 | ELSEVIER SCIENCE SA LAUSANNE |
| 源URL | [http://ir.wipm.ac.cn/handle/112942/12683]  |
| 专题 | 中国科学院武汉物理与数学研究所 |
| 作者单位 | 1.CHINESE ACAD SCI,WUHAN INST PHYS,LAB MAGNET RESONANCE & ATOM & MOL PHYS,WUHAN 430071,PEOPLES R CHINA 2.ZHENGZHOU UNIV,DEPT CHEM,ZHENGZHOU 450052,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | Yuan, HZ,Liu, YH,Wu, YJ,et al. Symmetrization reaction of mercurated ferrocenylimines. X-ray crystal structure of [Hg{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NC6H4-4-Br)}(2)][J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,1997,534(1-2):7-13. |
| APA | Yuan, HZ,Liu, YH,Wu, YJ,&Huo, SQ.(1997).Symmetrization reaction of mercurated ferrocenylimines. X-ray crystal structure of [Hg{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NC6H4-4-Br)}(2)].JOURNAL OF ORGANOMETALLIC CHEMISTRY,534(1-2),7-13. |
| MLA | Yuan, HZ,et al."Symmetrization reaction of mercurated ferrocenylimines. X-ray crystal structure of [Hg{(eta(5)-C5H5)Fe(eta(5)-C5H3CPh=NC6H4-4-Br)}(2)]".JOURNAL OF ORGANOMETALLIC CHEMISTRY 534.1-2(1997):7-13. |
入库方式： OAI收割
来源：武汉物理与数学研究所
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