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Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation

文献类型：期刊论文

作者Xu, Jiawei4; Zhang, Chong1; Qiu, Zexiong3; Lei, Zhenyu2; Chen, Bing2; Jiang, Jia-Xing1; Wang, Feng4
刊名MACROMOLECULAR CHEMISTRY AND PHYSICS
出版日期2017-11-01
卷号218期号:22
关键词Gas Adsorption Microporous Organic Polymers Separation Triphenylphosphine
ISSN号1022-1352
DOI10.1002/macp.201700275
文献子类Article
英文摘要Two kinds of novel triphenylphosphine-containing microporous organic polymers are designed and synthesized via palladium-catalyzed SonogashiraHagihara coupling condensation reaction of triphenylphosphine oxideand sulfide-based monomers with different arylethynylene linkers. The gas adsorption isotherms reveal that these polymers have strong binding affinity for CO2 with high CO2 adsorption capacity, although they have moderate Brunauer-Emmett-Teller surface area ranging from 684 to 883 m(2) g(-1). Among the resulting polymers, triphenylphosphine oxidetris(4-ethynylphenyl) amine exhibits the highest CO2 uptake capacity of 2.61 mmol g(-1) at 273 K and 1.13 bar with relatively high gas selectivity of 60.2 for CO2 over N-2 at 273 K.
WOS关键词POROUS AROMATIC FRAMEWORKS ; CARBON-DIOXIDE CAPTURE ; CO2 CAPTURE ; BUILDING-BLOCKS ; SURFACE-AREA ; NETWORKS SYNTHESIS ; SELECTIVE UPTAKE ; SORPTION ; CONSTRUCTION ; ENHANCEMENT
WOS研究方向Polymer Science
语种英语
WOS记录号WOS:000417214600004
出版者WILEY-V C H VERLAG GMBH
资助机构Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077) ; Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077) ; Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077) ; Natural Science Foundation of China(51103111 ; Natural Science Foundation of China(51103111 ; Education Ministry of China(NCET-12-0714) ; Education Ministry of China(NCET-12-0714) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Shaanxi Innovative Team of Key Science and Technology(2013KCT-17) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Fundamental Research Funds for the Central Universities(GK201501002) ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; Scientific Research Foundation for the Returned Overseas Chinese Scholars ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; State Key Laboratory of Luminescent Materials and Devices(2014-skllmd-11) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; Graduate Innovative Fund of Wuhan Institute of Technology(CX2016074) ; 21304055 ; 21304055 ; 21574077) ; 21574077)
源URL[http://ir.wipm.ac.cn/handle/112942/12752]  
专题中国科学院武汉物理与数学研究所
通讯作者Jiang, Jia-Xing; Wang, Feng
作者单位1.Shaanxi Normal Univ, Sch Mat Sci & Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China
2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Peoples R China
3.Wuhan Univ Technol, Int Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
4.Wuhan Inst Technol, Sch Chem Engn & Pharm, Key Lab Green Chem Proc, Minist Educ, Wuhan 430073, Peoples R China
推荐引用方式
GB/T 7714		 Xu, Jiawei,Zhang, Chong,Qiu, Zexiong,et al. Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2017,218(22).
APA Xu, Jiawei.,Zhang, Chong.,Qiu, Zexiong.,Lei, Zhenyu.,Chen, Bing.,...&Wang, Feng.(2017).Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation.MACROMOLECULAR CHEMISTRY AND PHYSICS,218(22).
MLA Xu, Jiawei,et al."Synthesis and Characterization of Functional Triphenylphosphine-Containing Microporous Organic Polymers for Gas Storage and Separation".MACROMOLECULAR CHEMISTRY AND PHYSICS 218.22(2017).

入库方式： OAI收割

来源：武汉物理与数学研究所

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