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Hydrophobic Solid Acids and Their Catalytic Applications in Green and Sustainable Chemistry

文献类型：期刊论文

作者Liu, Fujian5; Dai, Sheng2; Xiao, Feng-Shou1; Zheng, Anmin4; Huang, Kuan3
刊名ACS CATALYSIS
出版日期2018
卷号8期号:1页码:372-391
关键词Solid Acids Nanoporous Materials Hydrophobicity Acid Catalysis Green And Sustainable Chemistry
ISSN号2155-5435
DOI10.1021/acscatal.7b03369
文献子类Review
英文摘要Acid catalysts are widely used in petrochemical reactions, the synthesis of fine chemicals, and biomass conversions in industry. To comply with the principles of green and sustainable chemistry, much attention is being paid to the replacement of traditional liquid acids with solid acid catalysts. Normally, solid acids exhibit hydrophilicity because of the unique hydrophilic nature of the acidic sites on their surfaces. Water, as a typical solvent, byproduct, or negative component in a variety of acid-catalyzed reactions, may be adsorbed on solid acids and then cause the deactivation of catalytic sites or hydrolysis of the frameworks. The development of solid acids with suitable hydrophobicity largely overcomes these issues and enhances their catalytic activities and reusability. This Review discusses some recent advances in the preparation of novel solid acids with controllable wettability and suitable hydrophobicity and highlights their application in catalyzing various reactions such as esterification, transesterification, acylation, condensation, hydration, and depolymerization of crystalline cellulose. In addition, this Review discusses how the hydrophobicity of solid acids is affected by their structures, surface characteristics, and acid centers, and determines the principles for designing solid acids with high catalytic activity and good reusability. It is instructive for researchers who are interested in designing new kinds of solid acids with improved efficiency and reusability for applications in green and sustainable chemistry.
WOS关键词ORDERED MESOPOROUS POLYMERS ; METAL-ORGANIC FRAMEWORKS ; WATER-TOLERANT CATALYSIS ; STRONG PROTONIC ACID ; SN-BETA ZEOLITE ; SULFONIC-ACID ; IONIC LIQUIDS ; HETEROGENEOUS CATALYSTS ; CARBON NANOTUBES ; BIODIESEL PRODUCTION
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000419751100040
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China(21573150 ; National Natural Science Foundation of China(21573150 ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; 21203122 ; 21203122 ; 21522310 ; 21522310 ; 91645112 ; 91645112 ; 21403192) ; 21403192) ; National Natural Science Foundation of China(21573150 ; National Natural Science Foundation of China(21573150 ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; 21203122 ; 21203122 ; 21522310 ; 21522310 ; 91645112 ; 91645112 ; 21403192) ; 21403192) ; National Natural Science Foundation of China(21573150 ; National Natural Science Foundation of China(21573150 ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; 21203122 ; 21203122 ; 21522310 ; 21522310 ; 91645112 ; 91645112 ; 21403192) ; 21403192) ; National Natural Science Foundation of China(21573150 ; National Natural Science Foundation of China(21573150 ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Natural Science Foundation of Zhejiang Province(LY15B030002) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; Key Research Program of Frontier Sciences, CAS(QYZDB-SSW-SLH026) ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; US Department of Energy, Office of Science, Basic Energy Sciences, Chemical Sciences, Geo-sciences, & Biosciences Division ; 21203122 ; 21203122 ; 21522310 ; 21522310 ; 91645112 ; 91645112 ; 21403192) ; 21403192)
源URL[http://ir.wipm.ac.cn/handle/112942/12788]  
专题中国科学院武汉物理与数学研究所
通讯作者Dai, Sheng; Xiao, Feng-Shou; Zheng, Anmin
作者单位1.Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China
2.Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA
3.Nanchang Univ, Sch Resources Environm & Chem Engn, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, Nanchang 330031, Jiangxi, Peoples R China
4.Chinese Acad Sci, Natl Ctr Magnet Resonance Wuhan, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Hubei, Peoples R China
5.Fuzhou Univ, Sch Chem Engn, NERC CFC, Gongye Rd 523, Fuzhou 350002, Fujian, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Fujian,Dai, Sheng,Xiao, Feng-Shou,et al. Hydrophobic Solid Acids and Their Catalytic Applications in Green and Sustainable Chemistry[J]. ACS CATALYSIS,2018,8(1):372-391.
APA Liu, Fujian,Dai, Sheng,Xiao, Feng-Shou,Zheng, Anmin,&Huang, Kuan.(2018).Hydrophobic Solid Acids and Their Catalytic Applications in Green and Sustainable Chemistry.ACS CATALYSIS,8(1),372-391.
MLA Liu, Fujian,et al."Hydrophobic Solid Acids and Their Catalytic Applications in Green and Sustainable Chemistry".ACS CATALYSIS 8.1(2018):372-391.

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来源：武汉物理与数学研究所

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