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Influence of Fluoride Ions on the Structure-directing Effect of Organic Amine in the Synthesis of Aluminophosphate Open-frameworks

文献类型：期刊论文

作者Tian Ye1,3; Xu Jun2; Wang Zi1; Deng Feng2; Xu Ruren1; Yan Wenfu1
刊名CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
出版日期2017-12-01
卷号33期号:6页码:853-859
ISSN号1005-9040
关键词Zeolite Aluminophosphate Open-framework Structure-directing Effect Fluoride
DOI10.1007/s40242-017-7131-9
文献子类Article
英文摘要The crystallization behavior of the initial mixture with the composition of Al2O3:4.0P(2)O(5):3.0 diethylenetriamine(DETA):xHF:153H(2)O was investigated at 180 degrees C, where 0 <= x <= 3 if x <= 1.8, three-dimensional open framework aluminophosphate AlPO-CJ3 I was obtained. If 2 a chain-like aluminophosphate(1) was obtained. The crystallization process of both compounds was investigated by means of powder X-ray diffraction(XRD) and the concentrations of Al and P in the liquid product during the crystallization process were analysed by means of inductively coupled plasma atomic emission spectroscopy(ICP-AES). The evolution of the coordination state of Al, P and F during the crystallization was monitored with Al-27, P-31 and F-19 MAS NMR technique. The influence of the fluoride ions and the source of fluoride ions on the structure-directing effect of DETA was discussed. It was found that the fluoride ions changed the crystallization direction of the initial mixture, i.e., the structure-directing effect of DETA, via altering the distribution or micro-structure of the inorganic fragments.
WOS关键词ZEOLITE SYNTHESIS ; MICROPOROUS ALUMINOPHOSPHATES ; FLUOROALUMINOPHOSPHATE CHAIN ; LAYERED ALUMINOPHOSPHATES ; CRYSTALLIZATION PROCESS ; TEMPERATURE-DEPENDENCE ; MOLECULAR-SIEVES ; SILICA ZEOLITE ; INITIAL-STAGE ; PIPERAZINE
WOS研究方向Chemistry
语种英语
出版者HIGHER EDUCATION PRESS
WOS记录号WOS:000426019100001
资助机构National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) ; National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) ; National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) ; National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; Programme of Introducing Talents of Discipline to Universities(the 111 Project), China(B17020) ; 21320102001 ; 21320102001 ; 21621001) ; 21621001)
源URL[http://ir.wipm.ac.cn/handle/112942/12872]  
专题中国科学院武汉物理与数学研究所
通讯作者Yan Wenfu
作者单位1.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
2.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China
3.Jilin Prov Prod Qual Supervis Testing Inst, Changchun 130012, Jilin, Peoples R China
推荐引用方式
GB/T 7714		 Tian Ye,Xu Jun,Wang Zi,et al. Influence of Fluoride Ions on the Structure-directing Effect of Organic Amine in the Synthesis of Aluminophosphate Open-frameworks[J]. CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,2017,33(6):853-859.
APA Tian Ye,Xu Jun,Wang Zi,Deng Feng,Xu Ruren,&Yan Wenfu.(2017).Influence of Fluoride Ions on the Structure-directing Effect of Organic Amine in the Synthesis of Aluminophosphate Open-frameworks.CHEMICAL RESEARCH IN CHINESE UNIVERSITIES,33(6),853-859.
MLA Tian Ye,et al."Influence of Fluoride Ions on the Structure-directing Effect of Organic Amine in the Synthesis of Aluminophosphate Open-frameworks".CHEMICAL RESEARCH IN CHINESE UNIVERSITIES 33.6(2017):853-859.

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来源：武汉物理与数学研究所

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