Unusual bulky solvent molecule encapsulation in the organic-amine-occupied 10-membered ring channels of aluminophosphate molecular sieve AlPO4-11
文献类型:期刊论文
作者 | Guo, Junhui2; Wang, Chao1; Xu, Jun1; Deng, Feng1; Yan, Wenfu2; Shi, Wei3; Xu, Ruren2 |
刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
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出版日期 | 2018-02-01 |
卷号 | 88页码:6-10 |
关键词 | Zeolites Aluminophosphate Hydrothermal Synthesis Solvothermal Synthesis Triethylene Glycol Encapsulation |
ISSN号 | 1387-7003 |
DOI | 10.1016/j.inoche.2017.12.009 |
文献子类 | Article |
英文摘要 | Highly crystalline aluminophosphate molecular sieve AlPO4-11 was synthesized using both water and triethylene glycol (TEG) as solvent. The products were thoroughly characterized by powder X-ray diffraction analyses, thermogravimetric analyses (TGA), scanning electron microscope (SEM) analyses, and solid-state CP/MAS NMR analyses. The results showed that both AlPO4-11 s had high degree of crystallinity and good thermal stability. The AlPO4-11 synthesized with triethylene glycol had a different morphology from that synthesized with water. Thermogravimetric analysis (TGA) and C-13 CP/MAS NMR analyses showed that the bulky organic solvent molecules were encapsulated in the organic-amine-occupied channels of AlPO4-11. This is the first observation that the bulky organic solvent molecules are included in the organic structure-directing agents occupied microporous aluminophosphate molecular sieves. The solvent molecules may act as a co-structure-directing agent in the formation of AlPO4-11 under solvothermal conditions. (C) 2017 Elsevier B.V. All rights reserved. |
WOS关键词 | OPEN-FRAMEWORK ALUMINOPHOSPHATE ; ENRICHED ZEOLITE-BETA ; SOLID-STATE NMR ; SOLVOTHERMAL SYNTHESIS ; CRYSTALLIZATION ; CRYSTALS ; DIPROPYLAMINE ; DEPENDENCE ; MECHANISM ; ALCOHOLS |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:000424309700002 |
出版者 | ELSEVIER SCIENCE BV |
资助机构 | National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; 111 Project(B17020) ; 111 Project(B17020) ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) ; National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; 111 Project(B17020) ; 111 Project(B17020) ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) ; National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; 111 Project(B17020) ; 111 Project(B17020) ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) ; National Natural Science Foundation of China(21571075 ; National Natural Science Foundation of China(21571075 ; National Key Research and Development Program of China(2016YFB0701100) ; National Key Research and Development Program of China(2016YFB0701100) ; 111 Project(B17020) ; 111 Project(B17020) ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team ; 21320102001 ; 21320102001 ; 21621001) ; 21621001) |
源URL | [http://ir.wipm.ac.cn/handle/112942/12874] ![]() |
专题 | 中国科学院武汉物理与数学研究所 |
通讯作者 | Yan, Wenfu |
作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Hubei, Peoples R China 2.Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China 3.Nankai Univ, Minist Educ, Key Lab Adv Energy Mat Chem, Tianjin 300071, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Junhui,Wang, Chao,Xu, Jun,et al. Unusual bulky solvent molecule encapsulation in the organic-amine-occupied 10-membered ring channels of aluminophosphate molecular sieve AlPO4-11[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2018,88:6-10. |
APA | Guo, Junhui.,Wang, Chao.,Xu, Jun.,Deng, Feng.,Yan, Wenfu.,...&Xu, Ruren.(2018).Unusual bulky solvent molecule encapsulation in the organic-amine-occupied 10-membered ring channels of aluminophosphate molecular sieve AlPO4-11.INORGANIC CHEMISTRY COMMUNICATIONS,88,6-10. |
MLA | Guo, Junhui,et al."Unusual bulky solvent molecule encapsulation in the organic-amine-occupied 10-membered ring channels of aluminophosphate molecular sieve AlPO4-11".INORGANIC CHEMISTRY COMMUNICATIONS 88(2018):6-10. |
入库方式: OAI收割
来源:武汉物理与数学研究所
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