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Porous Organic Polymers Constructed from Troger's Base as Efficient Carbon Dioxide Adsorbents and Heterogeneous Catalysts

文献类型：期刊论文

作者Dai, Zhifeng2,3,4; Tang, Yongquan2,3; Sun, Qi2,3; Liu, Xiaolong1; Meng, Xiangju2,3; Deng, Feng1; Xiao, Feng-Shou2,3
刊名CHEMCATCHEM
出版日期2018-04-24
卷号10期号:8页码:1900-1904
关键词Heterogeneous Catalysis Mesoporous Materials Organocatalysts Polymers Radical Reactions
ISSN号1867-3880
DOI10.1002/cctc.201701534
文献子类Article
英文摘要Through a radical solvothermal polymerization method, we synthesized two porous organic polymers based on Troger's base (POP-TB and POP-Me-TB) from the corresponding vinyl-functionalized monomers (2,8-divinyl-6H,12H-5,11-methanodibenzo[b,f]diazocine and 2,8-divinyl-4,10-dimethly-6H,12H-5,11-ethanodibenzo[b,f]diazocine; v-TB and v-Me-TB). The structure and porosity of these polymers are verified by using solid-state NMR spectroscopy, elemental analysis, SEM, TEM, N-2 sorption isotherms, and CO2 sorption tests. They exhibit high surface areas and moderate pore volumes, which give high CO2 adsorption capacities (90 and 71mgCO2 g(-1) at 273K and 60 and 44mgCO2 g(-1) at 298K for POP-TB and POP-Me-TB, respectively) under a CO2 pressure of 1bar. In addition, they display excellent catalytic activities together with highly stability as heterogeneous catalysts in the benchmark Knoevenagel reactions.
WOS关键词MICROPOROUS POLYIMIDE MEMBRANES ; HYDROLYTIC KINETIC RESOLUTION ; AEROBIC OXIDATION ; GAS SEPARATION ; CO2 CAPTURE ; HOMOGENEOUS CATALYSTS ; MESOPOROUS CARBON ; MICHAEL ADDITION ; PHOSPHAZENE BASE ; ROOM-TEMPERATURE
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000430659500026
出版者WILEY-V C H VERLAG GMBH
资助机构National Natural Science Foundation of China(21422306 ; National Natural Science Foundation of China(21422306 ; National Key Research and Development Program of China(2017YFC0211101) ; National Key Research and Development Program of China(2017YFC0211101) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; 91634201 ; 91634201 ; 21720102001) ; 21720102001) ; National Natural Science Foundation of China(21422306 ; National Natural Science Foundation of China(21422306 ; National Key Research and Development Program of China(2017YFC0211101) ; National Key Research and Development Program of China(2017YFC0211101) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; 91634201 ; 91634201 ; 21720102001) ; 21720102001) ; National Natural Science Foundation of China(21422306 ; National Natural Science Foundation of China(21422306 ; National Key Research and Development Program of China(2017YFC0211101) ; National Key Research and Development Program of China(2017YFC0211101) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; 91634201 ; 91634201 ; 21720102001) ; 21720102001) ; National Natural Science Foundation of China(21422306 ; National Natural Science Foundation of China(21422306 ; National Key Research and Development Program of China(2017YFC0211101) ; National Key Research and Development Program of China(2017YFC0211101) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; Zhejiang Provincial Natural Science Foundation(LR15B030001) ; 91634201 ; 91634201 ; 21720102001) ; 21720102001)
源URL[http://ir.wipm.ac.cn/handle/112942/12958]  
专题中国科学院武汉物理与数学研究所
通讯作者Meng, Xiangju; Xiao, Feng-Shou
作者单位1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan 430071, Hubei, Peoples R China
2.Zhejiang Univ, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China
3.Zhejiang Univ, Dept Chem, Hangzhou 310028, Zhejiang, Peoples R China
4.Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China
推荐引用方式
GB/T 7714		 Dai, Zhifeng,Tang, Yongquan,Sun, Qi,et al. Porous Organic Polymers Constructed from Troger's Base as Efficient Carbon Dioxide Adsorbents and Heterogeneous Catalysts[J]. CHEMCATCHEM,2018,10(8):1900-1904.
APA Dai, Zhifeng.,Tang, Yongquan.,Sun, Qi.,Liu, Xiaolong.,Meng, Xiangju.,...&Xiao, Feng-Shou.(2018).Porous Organic Polymers Constructed from Troger's Base as Efficient Carbon Dioxide Adsorbents and Heterogeneous Catalysts.CHEMCATCHEM,10(8),1900-1904.
MLA Dai, Zhifeng,et al."Porous Organic Polymers Constructed from Troger's Base as Efficient Carbon Dioxide Adsorbents and Heterogeneous Catalysts".CHEMCATCHEM 10.8(2018):1900-1904.

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来源：武汉物理与数学研究所

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