Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor
文献类型：期刊论文
| 作者 | Liu, Xinxin1,2; He, Tao1,4 ; Ge, Yuanzheng1,2; Li, Guomin3; Wu, Jingli1; Wang, Zhiqi1; Liu, Guangbo1; Wu, Jinhu1
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| 刊名 | JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 131页码:128-133 |
| 关键词 | Lignin Upgrading Dbd Plasma Anisole Guaiacol Catalytic Deaxygentadon |
| ISSN号 | 0165-2370 |
| DOI | 10.1016/j.jaap.2018.01.007 |
| 文献子类 | Article |
| 英文摘要 | Catalytic upgrading of anisole and guaiacol in an atmospheric dielectric barrier discharge (DBD) plasma reactor was studied. Compared to thermal upgrading in a fixed bed, the DBD plasma method can convert the model compound to benzene and toluene with high selectivity under relatively low temperature. The synergistic effect between H-2 plasma and Ni-Mo/SiO2 catalyst is crucial to the high deoxygenation rate. The primary reactions occurring during the DBD upgrading process include demethylation, methyl transfer, and hydrogenolysis. XRD spectra indicate that phase change should not be the primary reason for catalyst deactivation; GC-MS, NH3-TPD, and regeneration experiments show that carbon deposition is the cause for deactivation. NH3-TPD analysis reveals that a combination of medium and strong acid sites plays an important role in the hydrogenolysis of phenols to benzenes. The present work shows DBD catalytic upgrading as a promising route for the C-O bond hydrogenolysis reaction. |
| WOS关键词 | BIO-OIL ; PHASE HYDRODEOXYGENATION ; REACTION NETWORK ; ANISOLE ; GUAIACOL ; CONVERSION ; BIOMASS ; 4-METHYLANISOLE ; HYDROGENATION ; HYDROCARBONS |
| WOS研究方向 | Chemistry ; Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:000429393000014 |
| 出版者 | ELSEVIER SCIENCE BV |
| 资助机构 | National Natural Science Foundation of China(11375249) ; Foundation of Key Laboratory of Low-Carbon Conversion Science & Engineering, Shanghai Advanced Research Institute(KLLCCSE-201704) ; Sichuan Science and Technology Project(2017JZ0021) ; Natural Science Foundation of Shandong Province(ZR2016EEQ15) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/10757]  |
| 专题 | 青岛生物能源与过程研究所_热化学转化事业部 |
| 通讯作者 | He, Tao; Wu, Jinhu |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Qingdao Univ, Sch Chem & Chem Engn, Qingdao 266071, Peoples R China 4.Chinese Acad Sci, Key Lab Low Carbon Convers Sci & Engn, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xinxin,He, Tao,Ge, Yuanzheng,et al. Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,2018,131:128-133. |
| APA | Liu, Xinxin.,He, Tao.,Ge, Yuanzheng.,Li, Guomin.,Wu, Jingli.,...&Wu, Jinhu.(2018).Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor.JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,131,128-133. |
| MLA | Liu, Xinxin,et al."Upgrading of lignin pyrolytic-oil model compounds in a catalytic dielectric barrier discharge plasma reactor".JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS 131(2018):128-133. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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