Significantly Enhancing the Efficiency of a New Light-Harvesting Polymer with Alkylthio naphthyl Substituents Compared to Their Alkoxyl Analogs
文献类型：期刊论文
| 作者 | Huang, Gongyue1,4; Zhang, Jun1,4; Uranbileg, Nergui1; Chen, Weichao1,2 ; Jiang, Huanxiang1; Tan, Hua4; Zhu, Weiguo3,4; Yang, Renqiang1
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| 刊名 | ADVANCED ENERGY MATERIALS
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| 出版日期 | 2018-04-05 |
| 卷号 | 8期号:10 |
| 关键词 | Solar Cells Polymers Light Harvesting |
| ISSN号 | 1614-6832 |
| DOI | 10.1002/aenm.201702489 |
| 文献子类 | Article |
| 英文摘要 | In this work, a new benzo[1,2-b:4,5-b']dithiophene (BDT) building block containing alkylthio naphthyl as a side chain is designed and synthesized, and the resulting polymer, namely PBDTNS-BDD, shows a lower HOMO energy level than that of its alkoxyl naphthyl counterpart PBDTNO-BDD. An optimized photovoltaic device using PBDTNS-BDD as a donor exhibits power conversion efficiencies (PCE) of 8.70% and 9.28% with the fullerene derivative PC71BM and the fullerene-free small molecule ITIC as acceptors, respectively. Surprisingly, ternary blend devices based on PBDTNS-BDD and two acceptors, namely PC71BM and ITIC, shows a PCE of 11.21%, which is much higher than that of PBDTNO-BDD based ternary devices (7.85%) even under optimized conditions. |
| WOS关键词 | ORGANIC SOLAR-CELLS ; POWER CONVERSION EFFICIENCY ; WIDE-BANDGAP COPOLYMERS ; MOLECULAR-ENERGY LEVEL ; PHOTOVOLTAIC CELLS ; CONJUGATED POLYMERS ; SIDE-CHAIN ; PERFORMANCE ; BENZODITHIOPHENE ; ACCEPTOR |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000429535300016 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China(51773220 ; Ministry of Science and Technology of China(2014CB643501) ; 51573205 ; 61405209 ; 51673031) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/10799]  |
| 专题 | 中国科学院青岛生物能源与过程研究所 |
| 通讯作者 | Chen, Weichao; Zhu, Weiguo; Yang, Renqiang |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Bio Based Mat, Qingdao 266101, Peoples R China 2.Qingdao Univ, Coll Text & Clothing, Qingdao, Peoples R China 3.Changzhou Univ, Sch Mat Sci & Engn, Changzhou 213164, Peoples R China 4.Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Gongyue,Zhang, Jun,Uranbileg, Nergui,et al. Significantly Enhancing the Efficiency of a New Light-Harvesting Polymer with Alkylthio naphthyl Substituents Compared to Their Alkoxyl Analogs[J]. ADVANCED ENERGY MATERIALS,2018,8(10). |
| APA | Huang, Gongyue.,Zhang, Jun.,Uranbileg, Nergui.,Chen, Weichao.,Jiang, Huanxiang.,...&Yang, Renqiang.(2018).Significantly Enhancing the Efficiency of a New Light-Harvesting Polymer with Alkylthio naphthyl Substituents Compared to Their Alkoxyl Analogs.ADVANCED ENERGY MATERIALS,8(10). |
| MLA | Huang, Gongyue,et al."Significantly Enhancing the Efficiency of a New Light-Harvesting Polymer with Alkylthio naphthyl Substituents Compared to Their Alkoxyl Analogs".ADVANCED ENERGY MATERIALS 8.10(2018). |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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