Biomimetic Hybridization of Kevlar into Silk Fibroin: Nanofibrous Strategy for Improved Mechanic Properties of Flexible Composites and Filtration Membranes
文献类型：期刊论文
| 作者 | Lv, Lili1,2; Han, Xiangsheng1,2; Zong, Lu1; Li, Mingjie1 ; You, Jun1; Wu, Xiaochen1; Li, Chaoxu1,2
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| 刊名 | ACS NANO
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| 出版日期 | 2017-08-01 |
| 卷号 | 11期号:8页码:8178-8184 |
| 关键词 | Silk Fibroin Kevlar Nanofibrils Biomimetic Hybrid Nanofiltration |
| DOI | 10.1021/acsnano.7b03119 |
| 文献子类 | Article |
| 英文摘要 | Silk, one of the strongest natural biopolymers, was hybridized with Kevlar, one of the strongest synthetic polymers, through a biomimetic nanofibrous strategy. Regenerated silk materials have outstanding properties in transparency, biocompatibility, biodegradability and sustainability, and promising applications as diverse as in pharmaceutics, electronics, photonic devices and membranes. To compete with super mechanic properties of their natural counterpart, regenerated silk materials have been hybridized with inorganic fillers such as graphene and carbon nanotubes, but frequently lose essential mechanic flexibility. Inspired by the nanofibrous strategy of natural biomaterials (e.g., silk fibers, hemp and byssal threads of mussels) for fantastic mechanic properties, Kevlar was integrated in regenerated silk materials by combining nanometric fibrillation with proper hydrothermal treatments. The resultant hybrid films showed an ultimate stress and Young's modulus two times as high as those of pure regenerated SF films. This is not only because of the reinforcing effect of Kevlar nanofibrils, but also because of the increasing content of silk fl-sheets. When introducing Kevlar nanofibrils into the membranes of silk nanofibrils assembled by regenerated silk fibroin, the improved mechanic properties further enabled potential applications as pressure-driven nanofiltration membranes and flexible substrates of electronic devices. |
| WOS关键词 | SPIDER SILK ; ARAMID NANOFIBERS ; NANOCOMPOSITES ; STRENGTH ; DISSOLUTION ; TOUGHNESS ; GRAPHENE ; FIBRILS ; FIBERS ; FILMS |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000408520900067 |
| 资助机构 | Shandong "Taishan Youth Scholoar Program", Shandong Provincial Natural Science Foundation(JQ201609 ; Shandong Collaborative Innovation Center ; Chinese "1000 youth Talent Program", National Natural Science Foundation of China(21474125) ; ZR2016EEB25) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9568]  |
| 专题 | 青岛生物能源与过程研究所_仿生智能材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Songling Rd 189, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lv, Lili,Han, Xiangsheng,Zong, Lu,et al. Biomimetic Hybridization of Kevlar into Silk Fibroin: Nanofibrous Strategy for Improved Mechanic Properties of Flexible Composites and Filtration Membranes[J]. ACS NANO,2017,11(8):8178-8184. |
| APA | Lv, Lili.,Han, Xiangsheng.,Zong, Lu.,Li, Mingjie.,You, Jun.,...&Li, Chaoxu.(2017).Biomimetic Hybridization of Kevlar into Silk Fibroin: Nanofibrous Strategy for Improved Mechanic Properties of Flexible Composites and Filtration Membranes.ACS NANO,11(8),8178-8184. |
| MLA | Lv, Lili,et al."Biomimetic Hybridization of Kevlar into Silk Fibroin: Nanofibrous Strategy for Improved Mechanic Properties of Flexible Composites and Filtration Membranes".ACS NANO 11.8(2017):8178-8184. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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