Gas phase hydrodeoxygenation of anisole and guaiacol to aromatics with a high selectivity over Ni-Mo/SiO2
文献类型：期刊论文
| 作者 | He, Tao1 ; Liu, Xinxin1,2; Ge, Yuanzheng1,2; Han, Dezhi1; Li, Jianqing1,2; Wang, Zhiqi1; Wu, Jinhu1
|
| 刊名 | CATALYSIS COMMUNICATIONS
 |
| 出版日期 | 2017-12-01 |
| 卷号 | 102页码:127-130 |
| DOI | 10.1016/j.catcom.2017.09.011 |
| 文献子类 | Article |
| 英文摘要 | A very active Ni-Mo bimetallic catalyst supported on SiO2 was prepared for the hydrodeoxygenation (HDO) reaction of anisole and guaiacol under a H-2 partial pressure of 83 kPa. Generally, transition metal and their oxides were thought to have less HDO activity than others, such as sulfides, carbides, phosphides. However, this work achieved a novel deoxygenation result, where a high conversion (98.7%) at 673-693 degrees C and atmospheric pressure for the model compounds and high selectivity ( > 96%) to aromatic hydrocarbons (BTX) were obtained. Furthermore, the methyl transfer reaction is greatly promoted by abundant acid sites of the catalyst, leading to a low carbon-loss. The present work provides a promising way and new insight for an economic and efficient HDO process for the lignin-derived thermal degradation products. |
| WOS关键词 | MODEL COMPOUNDS ; PYROLYSIS OIL ; CATALYSTS ; LIGNIN ; BIOMASS ; MOS2 |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000413058800029 |
| 资助机构 | National Natural Science Foundation of China(11375249) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9597]  |
| 专题 | 青岛生物能源与过程研究所_热化学转化事业部 |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Biofuels, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Tao,Liu, Xinxin,Ge, Yuanzheng,et al. Gas phase hydrodeoxygenation of anisole and guaiacol to aromatics with a high selectivity over Ni-Mo/SiO2[J]. CATALYSIS COMMUNICATIONS,2017,102:127-130. |
| APA | He, Tao.,Liu, Xinxin.,Ge, Yuanzheng.,Han, Dezhi.,Li, Jianqing.,...&Wu, Jinhu.(2017).Gas phase hydrodeoxygenation of anisole and guaiacol to aromatics with a high selectivity over Ni-Mo/SiO2.CATALYSIS COMMUNICATIONS,102,127-130. |
| MLA | He, Tao,et al."Gas phase hydrodeoxygenation of anisole and guaiacol to aromatics with a high selectivity over Ni-Mo/SiO2".CATALYSIS COMMUNICATIONS 102(2017):127-130. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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