A Superior Polymer Electrolyte with Rigid Cyclic Carbonate Backbone for Rechargeable Lithium Ion Batteries
文献类型：期刊论文
| 作者 | Chai, Jingchao1,3; Liu, Zhihong1; Zhang, Jianjun1,3 ; Sun, Jinran2; Tian, Zeyi2; Ji, Yanying1; Tang, Kun2; Zhou, Xinhong2; Cui, Guanglei1
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| 刊名 | ACS APPLIED MATERIALS & INTERFACES
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| 出版日期 | 2017-05-31 |
| 卷号 | 9期号:21页码:17897-17905 |
| 关键词 | Lithium Ion Battery Polymer Electrolyte Poly(Vinylene Carbonate) Poly(Vinylidene Fluoride-h&Afluoropropylene) In Situ Polymerization |
| DOI | 10.1021/acsami.7b02844 |
| 文献子类 | Article |
| 英文摘要 | The fabricating process of Well-known Bellcore poly(vinylidene fluoride-hexaflutrropropyleoe) (PVcIF-HFP)-based polyrner, electrolytes is very complicated, tedious, and expensive owing to containing a large amount of fluorine substituents. Herein, a novel kind of poly(vinylene carbonate) (PVCA)-based polymer electrolyte is developed via a facile in situ polymerization method, which possesses the merits of good interfacial compatibility with electrodes. In addition, this polymer electrolyte presents a high ionic conductivity of 5.59 X 10(-4) S Cm-1 and a wide electrochemical stability window exceeding 4.8 V vs Li+/Li at ambient temperature. In addition, the rigid cyclic carbonate backbone of poly(vinylene carbonate) endows polymer electrolyte a superior mechanical property. The LiFe0.2Mn0.8PO4/graphite lithium ion batteries using this polymer electrolyte deliver good rate capability and excellent cyclability at room temperature. The superior performance demonstrates that the PVCA-based electrolyte via in situ polymerization is a potential alternative polymer elettrolyte for high-performance rechargeable lithium ion batteries. |
| WOS关键词 | ROOM-TEMPERATURE ; COMPOSITE ELECTROLYTES ; VINYLENE CARBONATE ; ELECTROCHEMICAL PERFORMANCE ; POSITIVE ELECTRODE ; ANODE ; NANOPARTICLES ; INTERPHASE ; STABILITY ; CATHODE |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000402691600026 |
| 资助机构 | National Science Foundation of China(51625204) ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105) ; "135" Projects Fund of the CAS-QIBEBT Director Innovation Foundation |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9649]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Technol Inst, Qingdao 266101, Peoples R China 2.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chai, Jingchao,Liu, Zhihong,Zhang, Jianjun,et al. A Superior Polymer Electrolyte with Rigid Cyclic Carbonate Backbone for Rechargeable Lithium Ion Batteries[J]. ACS APPLIED MATERIALS & INTERFACES,2017,9(21):17897-17905. |
| APA | Chai, Jingchao.,Liu, Zhihong.,Zhang, Jianjun.,Sun, Jinran.,Tian, Zeyi.,...&Cui, Guanglei.(2017).A Superior Polymer Electrolyte with Rigid Cyclic Carbonate Backbone for Rechargeable Lithium Ion Batteries.ACS APPLIED MATERIALS & INTERFACES,9(21),17897-17905. |
| MLA | Chai, Jingchao,et al."A Superior Polymer Electrolyte with Rigid Cyclic Carbonate Backbone for Rechargeable Lithium Ion Batteries".ACS APPLIED MATERIALS & INTERFACES 9.21(2017):17897-17905. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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