An interpenetrating network poly(diethylene glycol carbonate)-based polymer electrolyte for solid state lithium batteries
文献类型：期刊论文
| 作者 | Liu, Xiaochen1,2; Ding, Guoliang2 ; Zhou, Xinhong1; Li, Shizhen1,2; He, Weisheng1,2; Chai, Jingchao2; Pang, Chunguang2; Liu, Zhihong1,2; Cui, Guanglei2
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| 刊名 | JOURNAL OF MATERIALS CHEMISTRY A
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| 出版日期 | 2017-06-14 |
| 卷号 | 5期号:22页码:11124-11130 |
| DOI | 10.1039/c7ta02423a |
| 文献子类 | Article |
| 英文摘要 | Polycarbonate-based polymer electrolytes possess superior ionic conductivity at room temperature, higher lithium ion transference number and wider electrochemical stability window when compared with conventional poly(ethylene oxide)-based polymer electrolytes. Herein, the poly(diethylene glycol carbonate) dimethacrylate macromonomer (PDEC-DMA) was synthesized and the resultant interpenetrating network IPN-PDEC polymer electrolyte was developed via free radical in situ polymerization for polymer electrolyte Li metal batteries. This IPN-PDEC polymer electrolyte exhibited a decent ionic conductivity of 1.64 x 10(-4) S cm(-1) at room temperature and a wide electrochemical stability window (up to 4.5 V vs. Li+/Li). The LiFePO4/IPN-PDEC/Li and LiFe0.2Mn0.8PO4/IPN-PDEC/Li cells delivered excellent rate capability and cycling performance at room temperature. An all solid state lithium battery was also demonstrated by applying the as-prepared solid polymer electrolyte (SPE-PDEC) at a temperature of 100 degrees C, which displayed a superior cycling performance. Therefore, the IPN-PDEC network is a promising polymer electrolyte for solid state lithium batteries. |
| WOS关键词 | ION BATTERIES ; ELECTROCHEMICAL PROPERTIES ; CONDUCTIVITY ; COMPOSITE ; LIQUID ; PERFORMANCE ; MECHANISMS ; OXIDE) |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000402734600040 |
| 资助机构 | Strategic Priority Research Program of the Chinese Academy of Sciences(XDA09010105) ; National Natural Science Foundation for Distinguished Young Scholars of China(51625204) ; "135" Projects Fund of CAS-QIBEBT Director Innovation Foundation |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9660]  |
| 专题 | 青岛生物能源与过程研究所_仿生能源与储能系统团队 |
| 作者单位 | 1.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Ind Energy Storage Res Inst, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Xiaochen,Ding, Guoliang,Zhou, Xinhong,et al. An interpenetrating network poly(diethylene glycol carbonate)-based polymer electrolyte for solid state lithium batteries[J]. JOURNAL OF MATERIALS CHEMISTRY A,2017,5(22):11124-11130. |
| APA | Liu, Xiaochen.,Ding, Guoliang.,Zhou, Xinhong.,Li, Shizhen.,He, Weisheng.,...&Cui, Guanglei.(2017).An interpenetrating network poly(diethylene glycol carbonate)-based polymer electrolyte for solid state lithium batteries.JOURNAL OF MATERIALS CHEMISTRY A,5(22),11124-11130. |
| MLA | Liu, Xiaochen,et al."An interpenetrating network poly(diethylene glycol carbonate)-based polymer electrolyte for solid state lithium batteries".JOURNAL OF MATERIALS CHEMISTRY A 5.22(2017):11124-11130. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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