The Kinetics of the Electroreduction Reaction of Molecular Oxygen in a Series of Quinoline Media
文献类型：期刊论文
| 作者 | Cao, Fengting1; Sun, Xiaolin1; Sun, Shimei1; Zang, Zhao1; Li, Xichao1; Liu, Tao1; Ohsaka, Takeo2; Wu, Jianfei1 |
| 刊名 | JOURNAL OF THE ELECTROCHEMICAL SOCIETY
 |
| 出版日期 | 2017 |
| 卷号 | 164期号:6页码:H326-H330 |
| DOI | 10.1149/2.0901706jes |
| 文献子类 | Article |
| 英文摘要 | The quantitative investigations of the electroreduction of O-2 to O-2(-) at Au electrode in Q, IQ and a series of methylquinoline solvents were carried out using cyclic voltammetry (CV) and normal pulse voltammetry (NPV). The relevant kinetic parameters (i.e., the standard rate constant, k(o), and the cathodic transfer coefficient, alpha(c)) were evaluated by NPV. Results show that there is an inverse relationship of the formal potential (E-o,) to lowest unoccupied molecular orbital (LUMO) energy, indicating that O-2(-) is more stabilized in a solvent with lower LUMO; and a proportional relationship of k(o) to diffusion coefficient (D), indicating the solvent dynamics control of the electrode reactions. (C) 2017 The Electrochemical Society. All rights reserved. |
| WOS关键词 | REDUCTION REACTION ; ELECTRON-TRANSFER ; SUPEROXIDE ION ; DIFFUSION-COEFFICIENTS ; OSCILLATORY PHENOMENA ; APROTIC-SOLVENTS ; REDOX REACTION ; AQUEOUS-MEDIA ; POLYMER-FILM ; COUPLE |
| WOS研究方向 | Electrochemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000401607500011 |
| 资助机构 | Government of Japan ; National Natural Science Foundation of China(21673267) ; Qingdao Industrial Energy Storage Technology Institute |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9697]  |
| 专题 | 青岛生物能源与过程研究所_超电产业综合技术事业部 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Ind Energy Storage Res Inst, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan |
| 推荐引用方式 GB/T 7714 | Cao, Fengting,Sun, Xiaolin,Sun, Shimei,et al. The Kinetics of the Electroreduction Reaction of Molecular Oxygen in a Series of Quinoline Media[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2017,164(6):H326-H330. |
| APA | Cao, Fengting.,Sun, Xiaolin.,Sun, Shimei.,Zang, Zhao.,Li, Xichao.,...&Wu, Jianfei.(2017).The Kinetics of the Electroreduction Reaction of Molecular Oxygen in a Series of Quinoline Media.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,164(6),H326-H330. |
| MLA | Cao, Fengting,et al."The Kinetics of the Electroreduction Reaction of Molecular Oxygen in a Series of Quinoline Media".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 164.6(2017):H326-H330. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。