Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots
文献类型：期刊论文
| 作者 | Ji, Guijie1; Duan, Yanan1; Zhang, Shaochun1; Fei, Benhua2; Chen, Xiufang1; Yang, Yong1 |
| 刊名 | CHEMSUSCHEM
 |
| 出版日期 | 2017-09-11 |
| 卷号 | 10期号:17页码:3427-3434 |
| 关键词 | Alkyne Hydrogenation Carbon Materials Nanoparticles Semihydrogenation Palladium |
| DOI | 10.1002/cssc.201701127 |
| 文献子类 | Article |
| 英文摘要 | Highly dispersed palladium nanoparticles (Pd NPs) immobilized on heteroatom-doped hierarchical porous carbon supports (N,O-carbon) with large specific surface areas are synthesized by a wet chemical reduction method. The N,O-carbon derived from naturally abundant bamboo shoots is fabricated by a tandem hydrothermal-carbonization process without assistance of any templates, chemical activation reagents, or exogenous N or O sources in a simple and ecofriendly manner. The prepared Pd/N,O-carbon catalyst shows extremely high activity and excellent chemoselectivity for semihydrogenation of a broad range of alkynes to versatile and valuable alkenes under ambient conditions. The catalyst can be readily recovered for successive reuse with negligible loss in activity and selectivity, and is also applicable for practical gram-scale reactions. |
| WOS关键词 | NANOPOROUS GOLD CATALYST ; STEREOSELECTIVE SEMIHYDROGENATION ; CIS-ALKENES ; HYDROGENATION REACTIONS ; PALLADIUM ; EFFICIENT ; REDUCTION ; DESIGN ; WATER ; SUPERCAPACITORS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000410136800016 |
| 资助机构 | Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences(Y6710619KL) ; 13th Five-Year National key R D projects(2017YFD0600805) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9739]  |
| 专题 | 青岛生物能源与过程研究所_低碳催化转化团队 |
| 作者单位 | 1.Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Int Ctr Bamboo & Rattan, Beijing 100102, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, Guijie,Duan, Yanan,Zhang, Shaochun,et al. Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots[J]. CHEMSUSCHEM,2017,10(17):3427-3434. |
| APA | Ji, Guijie,Duan, Yanan,Zhang, Shaochun,Fei, Benhua,Chen, Xiufang,&Yang, Yong.(2017).Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots.CHEMSUSCHEM,10(17),3427-3434. |
| MLA | Ji, Guijie,et al."Selective Semihydrogenation of Alkynes Catalyzed by Pd Nanoparticles Immobilized on Heteroatom-Doped Hierarchical Porous Carbon Derived from Bamboo Shoots".CHEMSUSCHEM 10.17(2017):3427-3434. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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