Acceptor-rich bulk heterojunction polymer solar cells with balanced charge mobilities
文献类型：期刊论文
| 作者 | Zhu, Tingting1,2; Zhang, Yongchao1; Li, Yonghai1; Song, Xin2; Liu, Zhe2; Wen, Shuguang1; Bao, Xichang1; Sun, Mingliang2; Yang, Renqiang1 |
| 刊名 | ORGANIC ELECTRONICS
 |
| 出版日期 | 2017-12-01 |
| 卷号 | 51页码:16-24 |
| 关键词 | Wide Band-gap Acceptor-rich Blend Polymer Solar Cells Balanced Charge Mobilities |
| DOI | 10.1016/j.orgel.2017.08.031 |
| 文献子类 | Article |
| 英文摘要 | In this work, we reported efficient polymer solar cells with balanced hole/electron mobilities tuned by the acceptor content in bulk heterojunction blend films. The photovoltaic cells were fabricated with two new wide band-gap D-A polymers PBDDIDT and PBDDIDTT as the donor material. The molecular conformations of new polymers are carefully evaluated by theoretical calculations. The results of photovoltaic studies show that two devices reach their optimal conditions with rich PC71BM content up to 80% in blend films, which is uncommon with most of reported PSCs. The as-cast devices based on PBDDIDT and PBDDIDTT reveal good photovoltaic performance with PCE of 7.04% and 6.40%, respectively. The influence of PC71BM content on photovoltaic properties is further detailed studied by photoluminescence emission spectra, charge mobilities and heterojunction morphology. The results exhibit that more efficient charge transport between donor and acceptor occurs in rich PC71BM blend films. Meanwhile, the hole and electron mobilities are simultaneously enhanced and afford a good balance in rich PC71BM blend films (D/A, 1: 4) which is critical for the improvement of current density and fill factors. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS关键词 | POWER CONVERSION EFFICIENCY ; SMALL-MOLECULE ACCEPTOR ; OPEN-CIRCUIT VOLTAGE ; HIGH-PERFORMANCE ; CONJUGATED POLYMER ; PHOTOVOLTAIC PERFORMANCE ; ELECTRON-ACCEPTORS ; ALKYL CHAINS ; DONOR ; COPOLYMERS |
| WOS研究方向 | Materials Science ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000418101600004 |
| 资助机构 | National Natural Science Foundation of China(21502205 ; Ministry of Science and Technology of China(2016YFE0115000) ; China Postdoctoral Science Foundation(2016T90656) ; 51573205) |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9825]  |
| 专题 | 青岛生物能源与过程研究所_先进有机功能材料团队 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Ocean Univ China, Inst Mat Sci & Engn, Qingdao 266100, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Tingting,Zhang, Yongchao,Li, Yonghai,et al. Acceptor-rich bulk heterojunction polymer solar cells with balanced charge mobilities[J]. ORGANIC ELECTRONICS,2017,51:16-24. |
| APA | Zhu, Tingting.,Zhang, Yongchao.,Li, Yonghai.,Song, Xin.,Liu, Zhe.,...&Yang, Renqiang.(2017).Acceptor-rich bulk heterojunction polymer solar cells with balanced charge mobilities.ORGANIC ELECTRONICS,51,16-24. |
| MLA | Zhu, Tingting,et al."Acceptor-rich bulk heterojunction polymer solar cells with balanced charge mobilities".ORGANIC ELECTRONICS 51(2017):16-24. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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