A Delicately Designed Sulfide Graphdiyne Compatible Cathode for High-Performance Lithium/Magnesium-Sulfur Batteries
文献类型：期刊论文
| 作者 | Du Huiping; Zhang Zhonghua; He Jianjiang; Cui Zili; Chai Jingchao; Ma Jun; Yang Ze; Huang Changshui; Cui Guanglei |
| 刊名 | Small
 |
| 出版日期 | 2017-09-28 |
| 卷号 | 13期号:44页码:1702277 |
| DOI | 10.1002/smll.201702277 |
| 文献子类 | Article |
| 英文摘要 | Novel sulfur cathodes hold the key to the development of metal-sulfur batteries, the promising candidate of next-generation high-energy-storage systems. Herein, a fascinating sulfur cathode based on sulfide graphdiyne (SGDY) is designed with a unique structure, which is composed of a conducting carbon skeleton with high Li+ mobility and short sulfur energy-storing unites. The SGDY cathode can essentially avoid polysulfide dissolution and be compatible with commercially available carbonate-based electrolytes and Grignard reagent-based electrolytes (all phenyl complex (APC) type electrolytes). Both the assembled Li-S and Mg-S batteries exhibit excellent electrochemical performances including large capacity, superior rate capability, high capacity retention, and high Coulombic efficiency. More importantly, this is the first implementation case of a reliable Mg-S system based on nucleophilic APC electrolytes. |
| WOS关键词 | LI-S BATTERIES ; LITHIUM STORAGE ; POROUS CARBON ; CYCLING STABILITY ; GRAPHENE OXIDE ; POLYSULFIDE ; ELECTROLYTE ; CAPACITY ; NITROGEN ; RAMAN |
| WOS研究方向 | Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter |
| 语种 | 英语 |
| WOS记录号 | WOS:000416040600009 |
| 资助机构 | Qingdao Key Lab of Solar Energy Utilization and Energy Storage Technology National Natural Science Foundation of China 21271180 Key Technology Research Projects of Qingdao 13-CX-10 |
| 源URL | [http://ir.qibebt.ac.cn/handle/337004/9886]  |
| 专题 | 青岛生物能源与过程研究所_新型能源碳素材料团队 |
| 作者单位 | 1.中国科学院青岛生物能源与过程研究所 2.中国科学院大学 |
| 推荐引用方式 GB/T 7714 | Du Huiping,Zhang Zhonghua,He Jianjiang,et al. A Delicately Designed Sulfide Graphdiyne Compatible Cathode for High-Performance Lithium/Magnesium-Sulfur Batteries[J]. Small,2017,13(44):1702277. |
| APA | Du Huiping.,Zhang Zhonghua.,He Jianjiang.,Cui Zili.,Chai Jingchao.,...&Cui Guanglei.(2017).A Delicately Designed Sulfide Graphdiyne Compatible Cathode for High-Performance Lithium/Magnesium-Sulfur Batteries.Small,13(44),1702277. |
| MLA | Du Huiping,et al."A Delicately Designed Sulfide Graphdiyne Compatible Cathode for High-Performance Lithium/Magnesium-Sulfur Batteries".Small 13.44(2017):1702277. |
入库方式： OAI收割
来源：青岛生物能源与过程研究所
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