Sustainable Preparation of LiNii(1/3)Co(1/3)Mn(1/3)O(2)-V2O5 Cathode Materials by Recycling Waste Materials of Spent Lithium-Ion Battery and Vanadium-Bearing Slag
文献类型：期刊论文
| 作者 | Meng, Xiangqi1,2; Cao, Hongbin1,2; Hao, Jie2; Ning, Pengge2; Xu, Gaojie2; Sun, Zhi2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 6期号:5页码:5797-5805 |
| 关键词 | LiNi1/3Co1/3Mn1/3O2-V2O5 Cathode materials Sustainable preparation Spent lithium-ion batteries |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.7b03880 |
| 英文摘要 | Waste streams containing heavy metals are always of concern from both environmental and resource depleting points of view. The challenges are in most cases related to the effectiveness for high-value-added materials recovery from such waste, with which the environmental impacts during recycling shall be low. In this research, two typical heavy-metal-containing waste streams, i.e., spent lithium-ion batteries and vanadium-bearing slag, were simultaneously treated, and this enables regeneration of the LiNi1/3Co1/3Mn1/3O2 cathode materials which was considered difficult because of the dislocation of nickel and lithium ions during electrochemical performance. By using the intermediate product during vanadium-bearing slag treatment, the vanadium-embedded cathode material can be prepared which delivers excellent electrochemical performances with a specific capacity of 156.3 mA h g(-1) after 100 cycles at 0.1C with the capacity retention of 90.6%; even the additive amount is only 5%. A thin layer of vanadium oxide is found to be effective to promote electrochemical performance of the cathode material. Using the principles of green chemistry, this process enables high-performance cathode material regeneration without introducing extraction chemicals and with much lower environmental impacts as compared to traditional metallurgical technologies. |
| WOS关键词 | POSITIVE ELECTRODE MATERIALS ; IRREVERSIBLE CAPACITY LOSS ; CLOSED-LOOP PROCESS ; ELECTROCHEMICAL PROPERTIES ; VALUABLE METALS ; ACTIVE MATERIAL ; ENERGY-STORAGE ; RECOVERY ; PERFORMANCE ; ACID |
| 资助项目 | National Science Fund for Distinguished Young Scholars of China[51425405] ; National Science Fund for Distinguished Young Scholars of China[L1624051] ; 1000 Talents Program of China ; Key Program of Chinese Academy of Sciences[KFZD-SW-315] ; National Natural Science Foundation of China[51425405] ; Beijing Municipal Science & Technology Commission[Z171100002217028] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000431927500017 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Science Fund for Distinguished Young Scholars of China ; 1000 Talents Program of China ; Key Program of Chinese Academy of Sciences ; National Natural Science Foundation of China ; Beijing Municipal Science & Technology Commission |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/24596]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Sun, Zhi |
| 作者单位 | 1.Tianjin Univ, Sch Chem Engn & Technol, 135 Yaguan Rd,Haihe Educ Pk, Tianjin 300350, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, Key Lab Green Proc & Engn, Beijing Engn Res Ctr Proc Pollut Control, 1 Beier St, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Meng, Xiangqi,Cao, Hongbin,Hao, Jie,et al. Sustainable Preparation of LiNii(1/3)Co(1/3)Mn(1/3)O(2)-V2O5 Cathode Materials by Recycling Waste Materials of Spent Lithium-Ion Battery and Vanadium-Bearing Slag[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2018,6(5):5797-5805. |
| APA | Meng, Xiangqi,Cao, Hongbin,Hao, Jie,Ning, Pengge,Xu, Gaojie,&Sun, Zhi.(2018).Sustainable Preparation of LiNii(1/3)Co(1/3)Mn(1/3)O(2)-V2O5 Cathode Materials by Recycling Waste Materials of Spent Lithium-Ion Battery and Vanadium-Bearing Slag.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,6(5),5797-5805. |
| MLA | Meng, Xiangqi,et al."Sustainable Preparation of LiNii(1/3)Co(1/3)Mn(1/3)O(2)-V2O5 Cathode Materials by Recycling Waste Materials of Spent Lithium-Ion Battery and Vanadium-Bearing Slag".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 6.5(2018):5797-5805. |
入库方式： OAI收割
来源：过程工程研究所
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