Carbon Dioxide Sequestration via Steelmaking Slag Carbonation in Alkali Solutions: Experimental Investigation and Process Evaluation
文献类型:期刊论文
作者 | Wang, Chen-Ye1,2; Bao, Wei-Jun2; Guo, Zhan-Cheng1; Li, Hui-Quan2 |
刊名 | ACTA METALLURGICA SINICA-ENGLISH LETTERS
![]() |
出版日期 | 2018-07-01 |
卷号 | 31期号:7页码:771-784 |
关键词 | Steelmaking Slag Dilute Alkali Solution Co2 Mineral Sequestration Process Evaluation |
ISSN号 | 1006-7191 |
DOI | 10.1007/s40195-017-0694-0 |
英文摘要 | Carbon dioxide mineral sequestration with steelmaking slag is a promising method for reducing carbon dioxide in a largescale setting. Existing calcium oxide or calcium hydroxide in steelmaking slag can be easily leached by water, and the formed calcium carbonate can be easily wrapped on the surface of unreacted steelmaking slag particles. Thus, further increase in the carbonation reaction rate can be prevented. Enhanced carbon dioxide mineral sequestration with steelmaking slag in dilute alkali solution was analysed in this study through experiments and process evaluation. Operating conditions, namely alkali concentration, reaction temperature and time, and liquid-to-solid ratio, were initially investigated. Then, the material and energy balance of the entire process was calculated, and the net carbon dioxide sequestration efficiency at different reaction times was evaluated. Results showed that dilute alkali solution participated in slowing down the leaching of active calcium in the steelmaking slag and in significantly improving carbonation conversion rate. The highest carbonation conversion rate of approximately 50% can be obtained at the optimal conditions of 20 g/L alkali concentration, 2 mL/L liquid-to-solid ratio, and 70 degrees C reaction temperature. Carbonation reaction time significantly influences the net carbon dioxide sequestration efficiency. According to calculation, carbon dioxide emission of 52.6 kg/tslag was avoided at a relatively long time of 120 min. |
WOS关键词 | Co2 Mineral Sequestration ; Precipitated Calcium-carbonate ; Steel Converter Slag ; Flue-gas Emissions ; Energy-consumption ; Capture |
资助项目 | National Natural Science Foundation of China[21300212] |
WOS研究方向 | Metallurgy & Metallurgical Engineering |
语种 | 英语 |
WOS记录号 | WOS:000433167400012 |
出版者 | CHINESE ACAD SCIENCES, INST METAL RESEARCH |
资助机构 | National Natural Science Foundation of China |
源URL | [http://ir.ipe.ac.cn/handle/122111/24637] ![]() |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Li, Hui-Quan |
作者单位 | 1.Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Natl Engn Lab Hydromet Cleaner Prod Technol, Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Chen-Ye,Bao, Wei-Jun,Guo, Zhan-Cheng,et al. Carbon Dioxide Sequestration via Steelmaking Slag Carbonation in Alkali Solutions: Experimental Investigation and Process Evaluation[J]. ACTA METALLURGICA SINICA-ENGLISH LETTERS,2018,31(7):771-784. |
APA | Wang, Chen-Ye,Bao, Wei-Jun,Guo, Zhan-Cheng,&Li, Hui-Quan.(2018).Carbon Dioxide Sequestration via Steelmaking Slag Carbonation in Alkali Solutions: Experimental Investigation and Process Evaluation.ACTA METALLURGICA SINICA-ENGLISH LETTERS,31(7),771-784. |
MLA | Wang, Chen-Ye,et al."Carbon Dioxide Sequestration via Steelmaking Slag Carbonation in Alkali Solutions: Experimental Investigation and Process Evaluation".ACTA METALLURGICA SINICA-ENGLISH LETTERS 31.7(2018):771-784. |
入库方式: OAI收割
来源:过程工程研究所
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。