Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction
文献类型：期刊论文
| 作者 | Liu, Hezhi1,2; Ji, Yongjun2; Zou, Xiujing1; Li, Jing2; Zhang, Yu2; Wang, Xueguang1; Zhong, Ziyi3; Su, Fabing2,4 |
| 刊名 | CATALYSTS
 |
| 出版日期 | 2018-04-01 |
| 卷号 | 8期号:4页码:12 |
| 关键词 | heterostructure hollow composite microsphere synergistic effect Rochow reaction |
| ISSN号 | 2073-4344 |
| DOI | 10.3390/catal8040144 |
| 英文摘要 | In this work, we report the design and synthesis of a series of heterostructured SnO2-CuO hollow microspherical catalysts (H-SnO2(x)-CuO, x is the weight ratio of Sn/Cu) for the Rochow reaction. The microspherical catalysts with nanosheets and nanoparticles as building blocks were prepared by a facile one-pot hydrothermal method coupled with calcination. When tested for the Rochow reaction, the prepared H-SnO2(0.2)-CuO composite exhibited higher dimethyldichlorosilane selectivity (88.2%) and Si conversion (36.7%) than the solid CuO, hollow CuO and other H-SnO2(x)-CuO microspherical samples, because in the former there is a stronger synergistic interaction between CuO and SnO2. |
| WOS关键词 | REDUCTION REACTION ; METHYL-CHLORIDE ; METHYLCHLOROSILANES ; COPPER ; PERFORMANCE ; MECHANISM ; SILICON ; CO ; OXIDATION ; KINETICS |
| 资助项目 | National Natural Science Foundation of China[21506224] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000435186400021 |
| 出版者 | MDPI |
| 资助机构 | National Natural Science Foundation of China |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/24897]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Ji, Yongjun; Wang, Xueguang; Su, Fabing |
| 作者单位 | 1.Shanghai Univ, Sch Mat Sci & Engn, State Key Lab Adv Special Steel, Shanghai 200072, Peoples R China 2.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 3.ASTAR, Inst Chem & Engn Sci, 1 Pesek Rd, Singapore 627833, Singapore 4.Shenyang Univ Chem Technol, Inst Ind Chem & Energy Technol, Shenyang 110142, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Hezhi,Ji, Yongjun,Zou, Xiujing,et al. Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction[J]. CATALYSTS,2018,8(4):12. |
| APA | Liu, Hezhi.,Ji, Yongjun.,Zou, Xiujing.,Li, Jing.,Zhang, Yu.,...&Su, Fabing.(2018).Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction.CATALYSTS,8(4),12. |
| MLA | Liu, Hezhi,et al."Controlled Synthesis of Heterostructured SnO2-CuO Composite Hollow Microspheres as Efficient Cu-Based Catalysts for the Rochow Reaction".CATALYSTS 8.4(2018):12. |
入库方式： OAI收割
来源：过程工程研究所
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