Stability of penicillin G in ionic liquid [Bmim]PF6
文献类型：期刊论文
| 作者 | Qi, Jingxian; Liu, Qingfen; Liu, Huizhou |
| 刊名 | CHINESE JOURNAL OF CHEMICAL ENGINEERING
 |
| 出版日期 | 2018-06-01 |
| 卷号 | 26期号:6页码:1430-1434 |
| 关键词 | Penicillin G Ionic liquids Stability Rearrangement Kinetics |
| ISSN号 | 1004-9541 |
| DOI | 10.1016/j.cjche.2018.02.030 |
| 英文摘要 | The extraction of penicillin G by ionic liquid [Bmim] PF6 has exhibited promising prospect. The stability of penicillin G is crucial for developing a green ionic liquid-based extraction technology. In this work, the stability of penicillin G in [Bmim] PF6 was systematically investigated. The results showed the stability of penicillin G was significantly influenced by pH and temperature. It tended to be more stable when pH value increased from 1.5 to 4.0 and the temperature gradually decreased. The half-life (t(1/2)) of penicillin G in [Bmim] PF6 was 17.7 h in the optimal technological condition (pH 2.0 and 10 degrees C), which is enough for the requirement of extraction technology. The reaction of penicillinG in [Bmim] PF6 followed the first order kinetics in the pHrange 2.0-4.0. Three isomers of penicillin G were found through rearrangement at pH 2.0, and their structures were not affected by temperature. (C) 2018 The Chemical Industry and Engineering Society of China, and Chemical Industry Press. All rights reserved. |
| WOS关键词 | AQUEOUS 2-PHASE SYSTEM ; WASTE-WATER ; DEGRADATION-PRODUCTS ; RESISTANCE GENES ; RECEIVING RIVER ; EXTRACTION ; TEMPERATURE ; SEPARATION ; SOLVENT ; FATE |
| 资助项目 | National Natural Science Foundation of China[21676272] ; Major Science and Technology Project of Water Pollution Control and Management in China[2017ZX07402003] ; Key Research Program of the Chinese Academy of Sciences[ZDRW-ZS-2016-5-3] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000440837100022 |
| 出版者 | CHEMICAL INDUSTRY PRESS |
| 资助机构 | National Natural Science Foundation of China ; Major Science and Technology Project of Water Pollution Control and Management in China ; Key Research Program of the Chinese Academy of Sciences |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/25492]  |
| 专题 | 中国科学院过程工程研究所 |
| 通讯作者 | Liu, Qingfen; Liu, Huizhou |
| 作者单位 | Chinese Acad Sci, Inst Proc Engn, CAS Key Lab Green Proc & Engn, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qi, Jingxian,Liu, Qingfen,Liu, Huizhou. Stability of penicillin G in ionic liquid [Bmim]PF6[J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING,2018,26(6):1430-1434. |
| APA | Qi, Jingxian,Liu, Qingfen,&Liu, Huizhou.(2018).Stability of penicillin G in ionic liquid [Bmim]PF6.CHINESE JOURNAL OF CHEMICAL ENGINEERING,26(6),1430-1434. |
| MLA | Qi, Jingxian,et al."Stability of penicillin G in ionic liquid [Bmim]PF6".CHINESE JOURNAL OF CHEMICAL ENGINEERING 26.6(2018):1430-1434. |
入库方式： OAI收割
来源：过程工程研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。