Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor
文献类型:期刊论文
作者 | Sun, Yong1; Yang, Gang2; Sun, Zhi3; Zhang, Lian4 |
刊名 | ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING |
出版日期 | 2017-07-01 |
卷号 | 12期号:4页码:518-526 |
ISSN号 | 1932-2135 |
关键词 | Fischer-tropsch Synthesis Fixed-bed Reactor Slurry Continuous Stirred Tank Reactor Comparative Study |
DOI | 10.1002/apj.2094 |
文献子类 | Article |
英文摘要 | Fischer-Tropsch synthesis was studied on mesoporous silica supported bimetallic Co-Ni catalyst in the fixed-bed reactor (FBR) and slurry continuous stirred tank reactor (CSTR) under different CO conversions by fixing other process parameters, for example, reaction temperature (300 degrees C), syngas ratio (2), and total pressure (3 MPa). The CO conversion is more sensitive in responding to the decrease of gas hour space velocity in FBR than that in CSTR. The intra-particle diffusional limitation was much improved in the CSTR system during Fischer-Tropsch synthesis due to the smaller particle size of the catalyst. The selectivity of gasoline fraction (C-5-C-13) was larger in CSTR than that in FBR when it was operated at relatively higher CO conversions (65%). The FBR tends to produce higher selectivity of longer-chain hydrocarbons than that in CSTR when the CO conversion was kept at around 22%. The increased 1-olefin selectivity was observed in both FBR and CSTR as CO conversion decrease with the FBR being more sensitive in responding to the CO conversion variation. The CSTR is found to be more effective in increasing light olefin fraction (C-2-C-6) when the CO conversion varies from 22 to 65%. (C) 2017 Curtin University of Technology and John Wiley & Sons, Ltd. |
WOS关键词 | Activated Carbon ; Membrane Reactor ; Heat-transfer ; Chain-length ; Iron ; Optimization ; Performance ; Water ; Removal ; Corncob |
WOS研究方向 | Engineering |
语种 | 英语 |
WOS记录号 | WOS:000409279400001 |
资助机构 | Anpeng High-Tech Energy and Resource-Company |
源URL | [http://ir.ipe.ac.cn/handle/122111/23204] |
专题 | 过程工程研究所_湿法冶金清洁生产技术国家工程实验室 |
作者单位 | 1.Edith Cowan Univ, Sch Engn, 270 Joondalup Dr, Joondalup, WA 6027, Australia 2.Anpeng Energy Grp, Beijing 100190, Peoples R China 3.Chinese Acad Sci, Inst Proc Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Beijing 100190, Peoples R China 4.Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia |
推荐引用方式 GB/T 7714 | Sun, Yong,Yang, Gang,Sun, Zhi,et al. Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor[J]. ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,2017,12(4):518-526. |
APA | Sun, Yong,Yang, Gang,Sun, Zhi,&Zhang, Lian.(2017).Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor.ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING,12(4),518-526. |
MLA | Sun, Yong,et al."Effect of CO conversion upon product distribution using bimetallic Co-Ni mesoporous silica catalyst for Fischer-Tropsch synthesis: a comparative study of fixed-bed reactor and slurry continuous stirred tank reactor".ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING 12.4(2017):518-526. |
入库方式: OAI收割
来源:过程工程研究所
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