In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance
文献类型：期刊论文
| 作者 | Wang, Ze1,2; Zeng, Ying1,2; Lin, Weigang1,2,3; Song, Wenli1,2 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2017-08-17 |
| 卷号 | 42期号:33页码:21040-21047 |
| 关键词 | In-situ Hydrodeoxygenation Biofuels Catalysis Hydrogen Donor |
| ISSN号 | 0360-3199 |
| DOI | 10.1016/j.ijhydene.2017.07.053 |
| 文献子类 | Article |
| 英文摘要 | In-situ hydrodeoxygenation of phenol with aqueous hydrogen donor over supported Ni catalyst was investigated. The supported Ni catalysts exerted very poor performance, if formic acid was used as the hydrogen donor. Catalyst modification by loading K, Na, Mg or La salt could not make the catalyst performance improved. If gaseous hydrogen was used as the hydrogen source the activity of Ni/Al2O3 was pretty high. CO2 was found poisonous to the catalysis, due to the competitive adoption of phenol with CO2. If formic acid was replaced by methanol, the catalyst performance improved remarkably, with major products of cyclohexanone and cyclohexanol. The better effect of methanol enlightened the application of the supported Ni catalyst in in-situ hydrodeoxygenation of phenol. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
| WOS关键词 | Temperature Coal-tar ; Clean Liquid Fuels ; Bio-oil ; Fast Pyrolysis ; Generated Hydrogen ; Pd Catalysts ; Formic-acid ; Biomass ; Nitride ; Oxide |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000410010600011 |
| 资助机构 | National Natural Science Foundation of China(51476180) ; National Basic Research Program of China (973 Program)(2014CB744304) |
| 源URL | [http://ir.ipe.ac.cn/handle/122111/23238]  |
| 专题 | 过程工程研究所_多相复杂系统国家重点实验室 |
| 作者单位 | 1.Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sinodanish Coll, Beijing 100190, Peoples R China 3.Tech Univ Denmark, Dept Chem & Biochem Engn, Bldg 229, DK-2800 Lyngby, Denmark |
| 推荐引用方式 GB/T 7714 | Wang, Ze,Zeng, Ying,Lin, Weigang,et al. In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2017,42(33):21040-21047. |
| APA | Wang, Ze,Zeng, Ying,Lin, Weigang,&Song, Wenli.(2017).In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,42(33),21040-21047. |
| MLA | Wang, Ze,et al."In-situ hydrodeoxygenation of phenol by supported Ni catalyst - explanation for catalyst performance".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 42.33(2017):21040-21047. |
入库方式： OAI收割
来源：过程工程研究所
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